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Answer:
E° = 1.24 V
Explanation:
Let's consider the following galvanic cell: Fe(s) | Fe²⁺(aq) || Ag⁺(aq) | Ag(s)
According to this notation, Fe is in the anode (where oxidation occurs) and Ag is in the cathode (where reduction occurs). The corresponding half-reactions are:
Anode: Fe(s) ⇒ Fe²⁺(aq) + 2 e⁻
Cathode: Ag⁺(aq) + 1 e⁻ ⇒ Ag(s)
The standard cell potential (E°) is the difference between the standard reduction potential of the cathode and the standard reduction potential of the anode.
E° = E°red, cat - E°red, an
E° = 0.80 V - (-0.44 V) = 1.24 V
Answer:
5.56 × 10⁻⁸
Explanation:
Step 1: Given data
- Concentration of the weak acid (Ca): 0.187 M
Step 2: Calculate the concentration of H⁺
We will use the following expression.
pH = -log [H⁺]
[H⁺] = antilog -pH = antilog -3.99 = 1.02 × 10⁻⁴ M
Step 3: Calculate the acid dissociation constant (Ka)
We will use the following expression.
![Ka = \frac{[H^{+}]^{2} }{Ca} = \frac{(1.02 \times 10^{-4})^{2} }{0.187} = 5.56 \times 10^{-8}](https://tex.z-dn.net/?f=Ka%20%3D%20%5Cfrac%7B%5BH%5E%7B%2B%7D%5D%5E%7B2%7D%20%7D%7BCa%7D%20%3D%20%5Cfrac%7B%281.02%20%5Ctimes%2010%5E%7B-4%7D%29%5E%7B2%7D%20%7D%7B0.187%7D%20%3D%205.56%20%5Ctimes%2010%5E%7B-8%7D)