Answer:
The correct order of increasing reactivity toward nucleophilic acyl substitution is E < D < C < A < F < B.
Explanation:
The stability of the leaving group best determines the manner of reactivity of carboxylates to nucleophilic substitution after the substitution of the nucleophile to the leaving group. The leaving group should, therefore, be protonated with hydrogen ion in the solution to form a stable molecule. From the given list: The leaving group for A, Ethyl thioacetate will be ethanethiol. For B, Acetyl chloride will be Hydrochloric acid. For C, Sodium acetate will be Sodium Hydroxide. For D, Ethyl acetate will be Ethanol. For E, Acetamide will be Ammonia, and for F, Acetic anhydride will be Ethanoic acid. The reactivity of the substitution reaction is dependent on the stability of these leaving groups. The stability of these leaving groups depends on their pKa, and the more the pKa, the lesser the acidity of the leaving group, and the lower the reactivity. Therefore, considering their pKa: A is 8.5, B is -7, C is 13.8, D is 15.9, E is 36, and F is 4.8. When we rearrange this pKa in descending order, we have E, D. C, A, F, B. Which is also the increased reactivity of the nucleophilic acyl substitution.
When the temperature of a gas within a rigid container decreases, the particles on average move more slowly and do not collide with one another or the container walls as often. It is the the ideal gas law that applies in this situation and states that a decrease in the temperature of a gas also results in a decrease in the pressure. Thus, automobile tyres which have a colder gas in the winter sometimes need additional air to provide suffiicient pressure.
Your answer is B: The outer electron of Adam B has moved to a higher energy state
Answer:
1.67mol/L
Explanation:
Data obtained from the question include:
Mole of solute (K2CO3) = 5.51 moles
Volume of solution = 3.30 L
Molarity =?
Molarity is simply the mole of solute per unit litre of the solution. It can be expressed mathematically as:
Molarity = mole of solute /Volume of solution
Molarity = 5.51 mol/3.30 L
Molarity = 1.67mol/L
Therefore, the molarity of K2CO3 is 1.67mol/L
