Explanation:
Contributing structures are the resonating structures which are formed due to the delocalization of electrons in a molecule.
The azide ion that is 
, is a symmetrical ion, all of whose contributing structures have formal charges.
Lone pair of central nitrogen atom in azide ion is in conjugation with the neighboring nitrogen atoms.
Contributing structures of azide ion are drawn in the image attached.
If the heat is absorbed, then the temperature will increase as well.
0.040 mol / dm³. (2 sig. fig.)
<h3>Explanation</h3>
in this question acts as a weak base. As seen in the equation in the question, produces 
rather than 
when it dissolves in water. The concentration of will likely be more useful than that of for the calculations here.
Finding the value of ![[\text{OH}^{-}]](https://tex.z-dn.net/?f=%5B%5Ctext%7BOH%7D%5E%7B-%7D%5D)
from pH:
Assume that 
,
.
![[\text{OH}^{-}] =10^{-\text{pOH}} =10^{-2.80} = 1.59\;\text{mol}\cdot\text{dm}^{-3}](https://tex.z-dn.net/?f=%5B%5Ctext%7BOH%7D%5E%7B-%7D%5D%20%3D10%5E%7B-%5Ctext%7BpOH%7D%7D%20%3D10%5E%7B-2.80%7D%20%3D%201.59%5C%3B%5Ctext%7Bmol%7D%5Ccdot%5Ctext%7Bdm%7D%5E%7B-3%7D)
.
Solve for ![[(\text{CH}_3)_3\text{N}]_\text{initial}](https://tex.z-dn.net/?f=%5B%28%5Ctext%7BCH%7D_3%29_3%5Ctext%7BN%7D%5D_%5Ctext%7Binitial%7D)
:
![\dfrac{[\text{OH}^{-}]_\text{equilibrium}\cdot[(\text{CH}_3)_3\text{NH}^{+}]_\text{equilibrium}}{[(\text{CH}_3)_3\text{N}]_\text{equilibrium}} = \text{K}_b = 1.58\times 10^{-3}](https://tex.z-dn.net/?f=%5Cdfrac%7B%5B%5Ctext%7BOH%7D%5E%7B-%7D%5D_%5Ctext%7Bequilibrium%7D%5Ccdot%5B%28%5Ctext%7BCH%7D_3%29_3%5Ctext%7BNH%7D%5E%7B%2B%7D%5D_%5Ctext%7Bequilibrium%7D%7D%7B%5B%28%5Ctext%7BCH%7D_3%29_3%5Ctext%7BN%7D%5D_%5Ctext%7Bequilibrium%7D%7D%20%3D%20%5Ctext%7BK%7D_b%20%3D%201.58%5Ctimes%2010%5E%7B-3%7D)
Note that water isn't part of this expression.
The value of Kb is quite small. The change in is nearly negligible once it dissolves. In other words,
![[(\text{CH}_3)_3\text{N}]_\text{initial} = [(\text{CH}_3)_3\text{N}]_\text{final}](https://tex.z-dn.net/?f=%5B%28%5Ctext%7BCH%7D_3%29_3%5Ctext%7BN%7D%5D_%5Ctext%7Binitial%7D%20%3D%20%5B%28%5Ctext%7BCH%7D_3%29_3%5Ctext%7BN%7D%5D_%5Ctext%7Bfinal%7D)
.
Also, for each mole of produced, one mole of 
was also produced. The solution started with a small amount of either species. As a result,
![[(\text{CH}_3)_3\text{NH}^{+}] = [\text{OH}^{-}] = 10^{-2.80} = 1.58\times 10^{-3}\;\text{mol}\cdot\text{dm}^{-3}](https://tex.z-dn.net/?f=%5B%28%5Ctext%7BCH%7D_3%29_3%5Ctext%7BNH%7D%5E%7B%2B%7D%5D%20%3D%20%5B%5Ctext%7BOH%7D%5E%7B-%7D%5D%20%3D%2010%5E%7B-2.80%7D%20%3D%201.58%5Ctimes%2010%5E%7B-3%7D%5C%3B%5Ctext%7Bmol%7D%5Ccdot%5Ctext%7Bdm%7D%5E%7B-3%7D)
.
![\dfrac{[\text{OH}^{-}]_\text{equilibrium}\cdot[(\text{CH}_3)_3\text{NH}^{+}]_\text{equilibrium}}{[(\text{CH}_3)_3\text{N}]_\textbf{initial}} = \text{K}_b = 1.58\times 10^{-3}](https://tex.z-dn.net/?f=%5Cdfrac%7B%5B%5Ctext%7BOH%7D%5E%7B-%7D%5D_%5Ctext%7Bequilibrium%7D%5Ccdot%5B%28%5Ctext%7BCH%7D_3%29_3%5Ctext%7BNH%7D%5E%7B%2B%7D%5D_%5Ctext%7Bequilibrium%7D%7D%7B%5B%28%5Ctext%7BCH%7D_3%29_3%5Ctext%7BN%7D%5D_%5Ctextbf%7Binitial%7D%7D%20%3D%20%5Ctext%7BK%7D_b%20%3D%201.58%5Ctimes%2010%5E%7B-3%7D)
,
![[(\text{CH}_3)_3\text{N}]_\textbf{initial} =\dfrac{[\text{OH}^{-}]_\text{equilibrium}\cdot[(\text{CH}_3)_3\text{NH}^{+}]_\text{equilibrium}}{\text{K}_b}](https://tex.z-dn.net/?f=%5B%28%5Ctext%7BCH%7D_3%29_3%5Ctext%7BN%7D%5D_%5Ctextbf%7Binitial%7D%20%3D%5Cdfrac%7B%5B%5Ctext%7BOH%7D%5E%7B-%7D%5D_%5Ctext%7Bequilibrium%7D%5Ccdot%5B%28%5Ctext%7BCH%7D_3%29_3%5Ctext%7BNH%7D%5E%7B%2B%7D%5D_%5Ctext%7Bequilibrium%7D%7D%7B%5Ctext%7BK%7D_b%7D)
,
![[(\text{CH}_3)_3\text{N}]_\text{initial} =\dfrac{(1.58\times10^{-3})^{2}}{6.3\times10^{-5}} = 0.040\;\text{mol}\cdot\text{dm}^{-3}](https://tex.z-dn.net/?f=%5B%28%5Ctext%7BCH%7D_3%29_3%5Ctext%7BN%7D%5D_%5Ctext%7Binitial%7D%20%3D%5Cdfrac%7B%281.58%5Ctimes10%5E%7B-3%7D%29%5E%7B2%7D%7D%7B6.3%5Ctimes10%5E%7B-5%7D%7D%20%3D%200.040%5C%3B%5Ctext%7Bmol%7D%5Ccdot%5Ctext%7Bdm%7D%5E%7B-3%7D)
.
Answer: An electron having a quantum number of one is closer to the nucleus
Explanation:
The Bohr model relies on electrostatic attraction between the nucleus and orbital electron. Hence, the closer an electron is to the nucleus the more closely it is held by the nucleus and the lesser its energy (the more stable the electron is and the more difficult it is to ionize it). The farther an electron is from the nucleus ( in higher shells or energy levels), the less the electrostatic attraction of such electron to the nucleus due to shielding effect. Hence it is less tightly held.
