Answer : The enthalpy change for the reaction is 1043 kJ/mol.
Explanation :
The given chemical reaction is:

As we know that:
The enthalpy change of reaction = E(bonds broken) - E(bonds formed)
![\Delta H=[(2\times B.E_{C\equiv O})+(1\times B.E_{O\equiv O})]-[2\times B.E_{C=O}]](https://tex.z-dn.net/?f=%5CDelta%20H%3D%5B%282%5Ctimes%20B.E_%7BC%5Cequiv%20O%7D%29%2B%281%5Ctimes%20B.E_%7BO%5Cequiv%20O%7D%29%5D-%5B2%5Ctimes%20B.E_%7BC%3DO%7D%5D)
Given:
= 1074 kJ/mol
= 499 kJ/mol
= 802 kJ/mol
Now put all the given values in the above expression, we get:
![\Delta H=[(2\times 1074kJ/mol)+(1\times 499kJ/mol)]-[2\times 802kJ/mol]](https://tex.z-dn.net/?f=%5CDelta%20H%3D%5B%282%5Ctimes%201074kJ%2Fmol%29%2B%281%5Ctimes%20499kJ%2Fmol%29%5D-%5B2%5Ctimes%20802kJ%2Fmol%5D)

Therefore, the enthalpy change for the reaction is 1043 kJ/mol.
Answer:
Explanation:
(a) Part 1:
reaction. This is a nucleophilic substitution reaction in which we have two steps. Firstly, chlorine, a good leaving group, leaves the carbon skeleton to form a relatively stable secondary carbocation. This carbocation is then attacked by the hydroxide anion, our nucleophile, to form the final product.
To summarize, this mechanism takes places in two separate steps. The mechanism is attached below.
Part 2:
reaction. This is a nucleophilic substitution reaction in which we have one step. Our nucleophile, hydroxide, attacks the carbon and then chlorine leaves simultaneously without an intermediate carbocation being formed.
The mechanism is attached as well.
(b) The rate determining step is the slow step. Formation of the carbocation has the greatest activation energy, so this is our rate determining step for
. For
, we only have one step, so the rate determining step is the attack of the nucleophile and the loss of the leaving group.
Answer:
Cations are positively charged atoms and hence we need to make the atom positively charged in order to get a cation
We know that an atom is neutral as a whole, so we have equal number of electrons and protons
since we cannot mess with the number of protons in an atom, we have to do it by altering the number of electrons
If we reduce the amount of electrons in an atom, the net charge will be positive and hence a cation will be formed
Answer:
Explanation:
moler mass of Cu is 63.546 g/mol. Since 63.546 g of copper has 6.022 x 10 power(23) atoms (Avogadro's number). = 9.5 x 10(power)21 atoms of copper.
Answer:
Compound
Explanation:
It has a definite composition throughout and can be made of more than one type of element.