Answer:
- final temperature (T2) = 748.66 K
- ΔU = w = 5620.26 J
- ΔH = 9367.047 J
- q = 0
Explanation:
ideal gas:
reversible adiabatic compression:
∴ q = 0
∴ w = - PδV
⇒ δU = δw
⇒ CvδT = - PδV
ideal gas:
⇒ PδV + VδP = RδT
⇒ PδV = RδT - VδP = - CvδT
⇒ RδT - RTn/PδP = - CvδT
⇒ (R + Cv,m)∫δT/T = R∫δP/P
⇒ [(R + Cv,m)/R] Ln (T2/T1) = Ln (P2/P1) = Ln (1 E6/1 E5) = 2.303
∴ (R + Cv,m)/R = (R + (3/2)R)/R = 5/2R/R = 2.5
⇒ Ln(T2/T1) = 2.303 / 2.5 = 0.9212
⇒ T2/T1 = 2.512
∴ T1 = 298 K
⇒ T2 = (298 K)×(2.512)
⇒ T2 = 748.66 K
⇒ ΔU = Cv,mΔT
⇒ ΔU = (3/2)R(748.66 - 298)
∴ R = 8.314 J/K.mol
⇒ ΔU = 5620.26 J
⇒ w = 5620.26 J
⇒ ΔH = ΔU + nRΔT
⇒ ΔH = 5620.26 J + (1 mol)(8.314 J/K.mol)(450.66 K)
⇒ ΔH = 5620.26 J + 3746.787 J
⇒ ΔH = 9367.047 J
Answer:
double replacement reaction or double displacement reaction,
Explanation:
double replacement reaction, double displacement reaction, is a chemical process involving the exchange of bonds between two non-reacting chemical species which results in the creation of products with similar or identical bonding affiliations
Classically, these reactions result in the precipitation of one product.
in thía case it is AgCl
Answer:
- 10.555 kJ/mol.
Explanation:
∵ ∆G°rxn = ∆H°rxn - T∆S°rxn.
Where, ∆G°rxn is the standard free energy change of the reaction (J/mol).
∆H°rxn is the standard enthalpy change of the reaction (J/mol).
T is the temperature of the reaction (K).
∆S°rxn is the standard entorpy change of the reaction (J/mol.K).
∵ ∆H°rxn = ∑∆H°products - ∑∆H°reactants
<em>∴ ∆H°rxn = (2 x ∆H°f NOCl) - (1 x ∆H°f Cl₂) - (2 x ∆H°f NO) </em>= (2 x 51.71 kJ/mol) - (1 x 0) - (2 x 90.29 kJ/mol) = - 77.16 kJ/mol.
∵ ∆S°rxn = ∑∆S°products - ∑∆S°reactants
<em>∴ ∆S°rxn = (2 x ∆S° NOCl) - (1 x ∆S° Cl₂) - (2 x ∆S° NO) </em>= (2 x 261.6 J/mol.K) - (1 x 223.0 J/mol.K) - (2 x 210.65 J/mol.K) =<em> - 121.1 J/mol.K. = - 0.1211 kJ/mol.K.</em>
<em></em>
∵ ∆G°rxn = ∆H°rxn - T∆S°rxn.
<em>∴ ∆G°rxn = ∆H°rxn - T∆S°rxn </em>= (- 77.16 kJ/mol) - (550 K)(- 0.1211 kJ/mol.K) = <em>- 10.555 kJ/mol.</em>
Potassium is the simplest form of matter and therefore can not be broken down by chemical change.
Answer:
Explanation:
Since the <em>rate constant</em> has units of <em>s⁻¹</em>, you can tell that the order of the reaction is 1.
Hence, the rate law is:
![r=d[A]/dt=-k[A]](https://tex.z-dn.net/?f=r%3Dd%5BA%5D%2Fdt%3D-k%5BA%5D)
Solving that differential equation yields to the well known equation for the rates of a first order chemical reaction:
![[A]=[A]_0e^{-kt}](https://tex.z-dn.net/?f=%5BA%5D%3D%5BA%5D_0e%5E%7B-kt%7D)
You know [A]₀, k, and t, thus you can calculate [A].
![[A]=0.548M\times e^{-3.6\cdot 10^{-4}/s\times99.2s}](https://tex.z-dn.net/?f=%5BA%5D%3D0.548M%5Ctimes%20e%5E%7B-3.6%5Ccdot%2010%5E%7B-4%7D%2Fs%5Ctimes99.2s%7D)
![[A]=0.529M](https://tex.z-dn.net/?f=%5BA%5D%3D0.529M)
