I think the answer is D no change. Though you add more CO2, but the pressure is not mentioned. If the pressure is constant and the reaction is already balanced, the H2O is also saturation and can not absorb more CO2.
I believe that the answer is 11.5
POH = - log [ OH⁻ ]
pOH = - log [ 1 x 10⁻⁹ ]
pOH = 9
Answer C
hope this helps!
Answer : The retention time is, 20 min
Explanation :
Retention time : It is defined as the amount of time a compound spends on the column after it has been injected.
Formula of retention time is:

Given:
Distance from injection point to center of peaks = 10 cm
Chart recorded speed = 0.5 cm/min
Now put all the given values in the above formula, we get:

Retention time = 20 min
Thus, the retention time is, 20 min