Answer:
b) pH = 9.25
Explanation:
- NH4+(aq) + H2O(l) ↔ NH3(aq) + H3O+(aq)
- NH3 + H2O ↔ NH4+ + OH-
- 2 H2O ↔ H3O+ + OH-
⇒ Kb = [ NH4+ ] * [ OH- ] / [ NH3 ] = 1.86 E-5......from literature
mass balance NH4+:
⇒ M NH4+ = [ NH4+ ] - [ OH- ]
∴ [ NH3 ] ≅ M NH4+ = 0.26 M
⇒ Kb = (( 0.26 + [ OH- ] )) * [ OH- ] / 0.26 = 1.86 E-5
⇒ 0.26 [ OH-] + [ OH- ]² = 4.836 E-6
⇒ [ OH- ]² + 0.26 [ OH- ] - 4.836 E-6 = 0
⇒ [ OH- ] = 1.859 E-5 M
⇒ pOH = - Log ( 1.859 E-5 )
⇒ pOH = 4.7305
⇒ pH = 14 - pOH = 9.269
1) (Hvap)(moles of water)=236.9783574kJ
(40.67)(105/18.02)
2) (change in temperature)(mass)(Cliquid)=43.9345172kJ
(100)(105/18.02)(75.4)/1000
3) (Hfus)(moles of water)=35.01942286kJ
(6.01)(105/18.02)
4) (change in temperature)(mass)(Csolid)=3.181465039kJ
(15)(105/18.02)(36.4)/1000
Total released=319.1137625kJ
B. Because there are 3 molecules in right and 2 molecules in the left, so entropy rises.
Answer:
Heat energy is the result of the movement of tiny particles called atoms, molecules or ions in solids, liquids and gases. Heat energy can be transferred from one object to another. the transfer or flow from one object to another is called heat.
hopefully this helped :3