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amm1812
3 years ago
8

Draw the structure of the neutral product formed in the reaction of dimethyl malonate and methyl vinyl ketone.

Chemistry
1 answer:
Dmitriy789 [7]3 years ago
3 0

Answer:

Explanation:

The reaction between dimethyl malonate which is an active methylene group with an (∝, β-unsaturated carbonyl compound) i.e methyl vinyl ketone is known as a Micheal Addition reaction. The reaction mechanism starts with the base attack on the β-carbon to remove the acidic ∝-hydrogens and form a carbanion. The carbanion formed(enolate ion) attacks the methyl vinyl ketone(i.e. a nucleophilic attack at the β-carbon) to give a Micheal addition product, this is followed by the protonation to give the neutral product.

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Answer:

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Explanation:

We have a buffer formed by a weak acid (C₆H₅COOH) and its conjugate base (C₆H₅COO⁻ coming from NaC₆H₅COO). We can find the concentration of C₆H₅COO⁻ (and therefore of NaC₆H₅COO) using the Henderson-Hasselbach equation.

pH = pKa + log [C₆H₅COO⁻]/[C₆H₅COOH]

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log [C₆H₅COO⁻] = pH - pKa + log [C₆H₅COOH]

log [C₆H₅COO⁻] = 3.87 - (-log 6.5 × 10⁻⁵) + log 0.40

[C₆H₅COO⁻] = [NaC₆H₅COO] = 0.19 M

We can find the mass of NaC₆H₅COO using the following expression.

M = mass NaC₆H₅COO / molar mass NaC₆H₅COO × liters of solution

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