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amm1812
3 years ago
8

Draw the structure of the neutral product formed in the reaction of dimethyl malonate and methyl vinyl ketone.

Chemistry
1 answer:
Dmitriy789 [7]3 years ago
3 0

Answer:

Explanation:

The reaction between dimethyl malonate which is an active methylene group with an (∝, β-unsaturated carbonyl compound) i.e methyl vinyl ketone is known as a Micheal Addition reaction. The reaction mechanism starts with the base attack on the β-carbon to remove the acidic ∝-hydrogens and form a carbanion. The carbanion formed(enolate ion) attacks the methyl vinyl ketone(i.e. a nucleophilic attack at the β-carbon) to give a Micheal addition product, this is followed by the protonation to give the neutral product.

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Answer:

a) K = 5.3175

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Explanation:

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∴ T = 25°C ≅ 298 K

∴ R = 8.314 E-3 KJ/K.mol

∴ ΔG° = - 4.140 KJ/mol

⇒ Ln K = - ( ΔG° ) / RT

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⇒ K = (0.45 M)/(1.6 M)

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