Answer:
![[Ag^{+}]=4.2\times 10^{-2}M](https://tex.z-dn.net/?f=%5BAg%5E%7B%2B%7D%5D%3D4.2%5Ctimes%2010%5E%7B-2%7DM)
Explanation:
Given:
[AgNO3] = 0.20 M
Ba(NO3)2 = 0.20 M
[K2CrO4] = 0.10 M
Ksp of Ag2CrO4 = 1.1 x 10^-12
Ksp of BaCrO4 = 1.1 x 10^-10
![Ksp=[Ba^{2+}][CrO_{4}^{2-}]](https://tex.z-dn.net/?f=Ksp%3D%5BBa%5E%7B2%2B%7D%5D%5BCrO_%7B4%7D%5E%7B2-%7D%5D)
![1.2\times 10^{-10}=(0.20)[CrO_{4}^{2-}]](https://tex.z-dn.net/?f=1.2%5Ctimes%2010%5E%7B-10%7D%3D%280.20%29%5BCrO_%7B4%7D%5E%7B2-%7D%5D)
![[CrO_{4}^{2-}]=\frac{1.2\times 10^{-10}}{(0.20)}= 6.0\times 10^{-10}](https://tex.z-dn.net/?f=%5BCrO_%7B4%7D%5E%7B2-%7D%5D%3D%5Cfrac%7B1.2%5Ctimes%2010%5E%7B-10%7D%7D%7B%280.20%29%7D%3D%206.0%5Ctimes%2010%5E%7B-10%7D)
Now,
![Ksp=[Ag^{+}]^{2}[CrO_{4}^{2-}]](https://tex.z-dn.net/?f=Ksp%3D%5BAg%5E%7B%2B%7D%5D%5E%7B2%7D%5BCrO_%7B4%7D%5E%7B2-%7D%5D)
![1.1\times 10^{-12}=[Ag^{+}]^{2}](6.0\times 10^{-10})](https://tex.z-dn.net/?f=1.1%5Ctimes%2010%5E%7B-12%7D%3D%5BAg%5E%7B%2B%7D%5D%5E%7B2%7D%5D%286.0%5Ctimes%2010%5E%7B-10%7D%29)
![[Ag^{+}]^{2}]=\frac{1.1\times 10^{-12}}{(6.0\times 10^{-10})}= 1.8\times 10^{-3}](https://tex.z-dn.net/?f=%5BAg%5E%7B%2B%7D%5D%5E%7B2%7D%5D%3D%5Cfrac%7B1.1%5Ctimes%2010%5E%7B-12%7D%7D%7B%286.0%5Ctimes%2010%5E%7B-10%7D%29%7D%3D%201.8%5Ctimes%2010%5E%7B-3%7D)
![[Ag^{+}]=\sqrt{1.8\times 10^{-3}}=4.2\times 10^{-2}M](https://tex.z-dn.net/?f=%5BAg%5E%7B%2B%7D%5D%3D%5Csqrt%7B1.8%5Ctimes%2010%5E%7B-3%7D%7D%3D4.2%5Ctimes%2010%5E%7B-2%7DM)
So, BaCrO4 will start precipitating when [Ag+] is 4.2 x 1.2^-2 M
Answer:
4.00 is the pH of the mixture
Explanation:
The ethyl amine reacts with HNO3 as follows:
C2H5NH2 + HNO3 → C2H5NH3⁺ + NO3⁻
To solve this question we need to find the moles of ethyl amine and the moles of HNO3:
<em>Moles C2H5NH2:</em>
0.0500L * (0.100mol/L) = 0.00500 moles ethyl amine
<em>Moles HNO3:</em>
0.201L * (0.025mol/L) = 0.005025 moles HNO3
That means HNO3 is in excess. The moles in excess are:
0.005025 moles HNO3 - 0.00500 moles ethyl amine =
2.5x10⁻⁵ moles HNO₃
In 50 + 201mL = 251mL = 0.251L:
2.5x10⁻⁵ moles HNO₃ / 0.251L = 9.96x10⁻⁵M = [H+]
As pH = -log [H+]
pH = -log 9.96x10⁻⁵M
pH = 4.00 is the pH of the mixture
A solvent is something that can have something else dissolved within it and turn into a homogenous solution, while the solute is that something else that can be dissolved into the solvent. Usually, the solvent is found in greater amount because most (except for rare cases) solvents have a saturation point that is below the equal-mass point.
