Answer:
The reactions free energy
Explanation:
From the question we are told that
The pressure of (NO) is
The pressure of (Cl) gas is
The pressure of nitrosly chloride (NOCl) is
The reaction is
⇆
From the reaction we can mathematically evaluate the (Standard state free energy ) as
The Standard state free energy for NO is constant with a value
The Standard state free energy for is constant with a value
The Standard state free energy for is constant with a value
Now substituting this into the equation
The pressure constant is evaluated as
Substituting values
The free energy for this reaction is evaluated as
Where R is gas constant with a value of
T is temperature in K with a given value of
Substituting value
Answer:
[ S2- ] = 4.0 E-47 M
Explanation:
- PbS(s) → Pb2+ + S2-
- HgS(s) → Hg2+ + S2-
∴ Ksp PbS = 3.4 E-28 = [Pb2+]*[S2-]
∴ [Pb2+] = 0.181 M
∴ Ksp HgS = 4.0 E-53 = [Hg2+]*[S2-]
∴ [Hg2+] = 0.174 M
∴ Ksp PbS > Ksp HgS ⇒ precipitate first Hg2+:
∴ [ Hg2+ ] = 1.0 E-6 M
⇒ [S2-] = 4.0 E-53 / 1.0 E-6 = 4.0 E-47 M
Explanation :
As we know that Mendeleev arranged the elements in horizontal rows and vertical columns of a table in order of their increasing relative atomic weights.
He placed the elements with similar nature in the same group.
According to the question, the atomic weight of iodine is less than the atomic weight of tellurium. So according to this, iodine should be placed before tellurium in Mendeleev's tables. But Mendeleev placed iodine after tellurium in his original periodic table.
However, iodine has similar chemical properties to chlorine and bromine. So, in order to make iodine queue up with chlorine and bromine in his periodic table, Mendeleev exchanged the positions of iodine and tellurium.
As we know that the positions of iodine and tellurium were reversed in Mendeleev's table because iodine has one naturally occurring isotope that is iodine-127 and tellurium isotopes are tellurium-128 and tellurium-130.
Due to high relative abundance of tellurium isotopes gives tellurium the greater relative atomic mass.
It is important because if the sample size is smaller, outliers could skew the data more than if it was large.