Answer:
First confirm the reaction is balanced:
C3H8 + 5O2 --> 3CO2 + 4H20 (3 cabon - check; 8 hydrogen - check; 10 oxygen - check).
a) In the equation there is a 5:1 ratio between propane and oxygen. We also know that number of mole is proportional to pressure and volume. Since pressure is constant (STP) then the volume of O2 is 7.2 * 5 = 36 litres.
b) For a near ideal gas that PV = nRT (combined gas law). So for 7.2 litres propane we find n(propane) = 101.3 * 7.2/8.314*298 ~ 0.29 mole (using metric units throughout for simplicity).
There is a 1:3 ratio between propane and CO2. Therefore 3 * 0.29 = 0.87 mole of CO2 is produced.
MW(CO2) ~ 44 g/mol. Therefore m(CO2) = 44 * 0.87 ~ 38.3 g
c) We know we need more oxygen than propane (due to the 1:5 ratio) so oxygen is the limiting reagent. Again Volume is proportional to number of mole and we see there is a 5:4 ratio between oxygen and water. Therefore the volume of water vapour produced will be (4/5) * 15 = 12 litres.
The other questions use the same technique and will give you some much needed practice.
Explanation:
Answer : The final pressure of the basketball is, 0.990 atm
Explanation :
Gay-Lussac's Law : It is defined as the pressure of the gas is directly proportional to the temperature of the gas at constant volume and number of moles.
or,
where,
= initial pressure = 1.10 atm
= final pressure = ?
= initial temperature = 
= initial temperature = 
Now put all the given values in the above equation, we get:
Thus, the final pressure of the basketball is, 0.990 atm
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Answer:
Explanation has been given below.
Explanation:
- Chloroform has three polar C-Cl bonds. Methylene chloride has two polar C-Cl bonds. So it is expected that chloroform should be more polar and posses higher dipole moment than methylene chloride.
- Two factors are liable for the opposite trend observed in dipole moments of methylene chloride and chloroform.
- First one is the number of hyperconjugative hydrogen atoms present in a molecule. Hyperconjugation occurs with vacant d-orbital of Cl atom. Hyperconjugation amplifies charge separation in a molecule resulting higher dipole moment.
- Methylene chloride has two hyperconjugative hydrogen atoms and chloroform has one hyperconjugative hydrogen atom.Therefore methylene chloride should have higher charge separation as compared to chloroform.
- Second one is induction of opposite polarity in a C-Cl bond by another C-Cl bond in a molecule. Higher the opposite induction of polarity, lower the charge separation in a molecule and hence lower the dipole moment of a molecule.
- Chloroform has three C-Cl bonds and methylene chloride has two C-Cl bonds. Therefore opposite induction is higher for chloroform resulting it's lower dipole moment.
