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Explanation:
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a sample gas is in the rigid cylinder with a movable piston the pressure of the gas is kept constant if the kelvin temperature o
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First we have to find Ka1 and Ka2
pKa1 = - log Ka1 so Ka1 = 0.059
pKa2 = - log Ka2 so Ka2 = 6.46 x 10⁻⁵
Looking at the values of equilibrium constants we can see that the first one is really big compared to second one. so, the pH will be affected mainly by the first ionization of the acid.
Oxalic acid is H₂C₂O₄
H₂C₂O₄ ⇄ H⁺ + HC₂O₄⁻
0.0356 M 0 0
0.0356 - x x x
Ka1 =![\frac{[H^+][HC2O4^-]}{[H2C2O4]}](https://tex.z-dn.net/?f=%20%5Cfrac%7B%5BH%5E%2B%5D%5BHC2O4%5E-%5D%7D%7B%5BH2C2O4%5D%7D%20)
= x² / 0.0356 - x
x = 0.025 M
pH = - log [H⁺] = - log (0.025) = 1.6
pKa1 = - log Ka1 so Ka1 = 0.059
pKa2 = - log Ka2 so Ka2 = 6.46 x 10⁻⁵
Looking at the values of equilibrium constants we can see that the first one is really big compared to second one. so, the pH will be affected mainly by the first ionization of the acid.
Oxalic acid is H₂C₂O₄
H₂C₂O₄ ⇄ H⁺ + HC₂O₄⁻
0.0356 M 0 0
0.0356 - x x x
Ka1 =
x = 0.025 M
pH = - log [H⁺] = - log (0.025) = 1.6
a. volume of NO : 41.785 L
b. mass of H2O : 18 g
c. volume of O2 : 9.52 L
<h3>Further explanation</h3>Given
Reaction
4 NH₃ (g) + 5 O2 (g) → 4 NO (g) + 6 H2O (l)
Required
a. volume of NO
b. mass of H2O
c. volume of O2
Solution
Assume reactants at STP(0 C, 1 atm)
Products at 1000 C (1273 K)and 1 atm
a. mol ratio NO : O2 from equation : 4 : 5, so mo NO :
volume NO at 1273 K and 1 atm
b. 15 L NH3 at STP ( 1mol = 22.4 L)
mol ratio NH3 : H2O from equation : 4 : 6, so mol H2O :
mass H2O(MW = 18 g/mol) :
c. mol NO at 1273 K and 1 atm :
mol ratio of NO : O2 = 4 : 5, so mol O2 :
Volume O2 at STP :