Answer: 48.95g
Explanation:
no. of moles of Cl2 = 39/(2*35.5) = 0.55 mol
no. of moles of Al = 34/27 = 1.26 mol
hence, aluminium is in excess so we'll do calculation using no. of moles of Cl2 as it will be the only reactant to be used up completely. So,
no of moles of AlCl3 = 2/3 * (0.55) = 0.367 mol
hence amount of AlCl3 = 0.367 * (27+3*35.5) = 48.95g
Answer:
(slow)xy2+z→xy2z (fast) c step1:step2:xy2+z2→xy2z2
Explanation:
Step1: xy2+z2→xy2z2 (slow)
Step2: xy2z2→xy2z+z (fast)
2XY 2 + Z 2 → 2XY 2 Z
Rate= k[xy2][z2]
When the two elementary steps are summed up, the result is equivalent to the stoichiometric equation. Hence, this mechanism is acceptable. The order of both elementary steps is 2, which is ‘≤3’; this also makes this mechanism acceptable. Furthermore, the rate equation aligns with the experimentally determined rate equation, and this also makes this mechanism acceptable. Therefore, since all the three rules have been observed, this mechanism is possible.
Answer:
MnO4⁻ (aq) + 8H⁺ (aq) + 5Fe³⁺ (aq) →Mn(aq)²⁺ + 4H2O (l) + 5Fe²⁺(aq)
Explanation:
a)
MnO4⁻ (aq) + 8H⁺ (aq) + 5e⁻ → Mn(aq)²⁺ + 4H2O (l)
b)
5Fe³⁺ (aq) +5e⁻ → 5Fe²⁺(aq)
c)
MnO4⁻ (aq) + 8H⁺ (aq) + 5Fe³⁺ (aq) →Mn(aq)²⁺ + 4H2O (l) + 5Fe²⁺(aq)
Answer:
True
Explanation:
We know that the zero-point-energy of a C-D system is quite lower than the zero point energy of the C-H bond so the C-D bond is stronger.
Kinetic isotope effect refers to the change in the rate of reaction owing to a change of one of the atoms of the reactants by replacing it with one of its isotopes.
Since we know that the C-D bond is stronger than the C-H bond, when we replace hydrogen with deuterium in a reaction's rate determining step we experience a little lag in the rate of reaction. This is referred to as the kinetic isotope effect in physical organic chemistry.
Answer:
Ha is more acidic than Hb because loss of Ha forms a resonance-stabilized conjugate base.
Explanation:
The carbon atom that is next to the carbonyl group in pentan-2-one is known as the alpha carbon atom, this carbon atom bears the Ha, the alpha hydrogen atoms.
Ha is more acidic than Hb because, loss of Ha leads to the formation of a resonance stabilized enolate ion. This resonance stabilization of the ion formed makes loss of Ha an easier process than loss of Hb, hence the answer above.
