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storchak [24]
3 years ago
13

A bottle containing air is initially at a temperature of 33 degrees C and a pressure of 0.81 atm. After being placed in the free

zer, the final temperature is 1 degrees C. What is the final pressure ?
Chemistry
1 answer:
Georgia [21]3 years ago
4 0

Answer:

The final pressure is 0.725 atm.

Explanation:

Gay Lussac's Law establishes the relationship between pressure and temperature of a gas when the volume is constant. This law says that when there is a constant volume, as the temperature increases, the pressure of the gas increases. And when the temperature is decreased, the pressure of the gas decreases. That is, pressure and temperature are directly proportional quantities.

Mathematically, Gay-Lussac's law states that, when a gas undergoes a constant volume transformation, the quotient of the pressure exerted by the gas temperature remains constant:

\frac{P}{T}  =k

When analyzing an initial state 1 and a final state 2, the following is satisfied:

\frac{P1}{T1}  =\frac{P2}{T2}

In this case:

  • P1= 0.81 atm
  • T1= 33 C= 306 K
  • P2= ?
  • T2= 1 C= 274 K

Replacing:

\frac{0.81 atm}{306 K}  =\frac{P2}{274 K}

Solving:

P2=274 K*\frac{0.81 atm}{306 K}

P2= 0.725 atm

<u><em>The final pressure is 0.725 atm.</em></u>

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Answer:

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b) the mass of helium = 1.14 grams

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Explanation:

Step 1: Data given

Volume of the tire = 860 mL

Total pressure = 120 psi

Temperature = 26°C

molar mass of air = 28.8 g/mol

Step 2:  Convert psi to atm

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120 psi) (1 atm / 14.7 psi) = 8.163

Step 4: Calculate moles

PV = nRT

 ⇒ with P = the pressure = 8.163 atm

⇒ with V = the volume = 860 mL = 0.860 L

⇒ with n = the number of moles = TO BE DETERMINED

⇒ with R = the universal gas constant = 0.08206 L*atm/K*mol

⇒ with T = the temperature = 26 °C = 299 Kelvin

n = (8163*0.860)/(0.08206*299)

n = 0.2861 moles of gas

Step 5: Calculate the mass of air in an air-filled tire.

Mass = moles * molar mass

Mass = (0.2861 moles of gas) (28.8 g/mol)  

Mass = 8.24 grams

Step 6: Calculate the mass of helium in a helium- filled tire.

mass of helium = 0.2861 moles of gas * 4 g/mol)  

mass of helium  = 1.14 grams

Step 7: What is the mass difference between the two?

Δmass=  8.24 grams -  1.14 grams

Δmass= 7.10 grams

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