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Alex
3 years ago
6

. If Kc is the equilibrium constant for a forward reaction, 2 A⇌ B, what is Kc' for the reaction 4 A⇌ 2B?

Chemistry
1 answer:
olganol [36]3 years ago
7 0

Answer:

(Kc)^2

Explanation:

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A gas sample occupies 350.0 mL at 546 mm Hg. What volume does the gas occupy at 652 mm Hg?​
leva [86]

Answer:

293.1 mL.

Explanation:

  • Boyle's law states that: at a constant temperature the pressure of a given mass of an ideal gas is inversely proportional to its volume.
  • It can be expressed as: <em>P₁V₁ = P₂V₂,</em>

P₁ = 546.0 mm Hg, V₁ = 350.0 mL.

P₂ = 652.0 mm Hg, V₂ = ??? mL.

<em>∴ V₂ = (P₁V₁)/(P₂)</em> = (546.0 mm Hg)(350.0 mL) / (652.0 mm Hg) = <em>293.1 mL.</em>

8 0
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Why is potassium less reactive than silver
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Because potassium is a gas that can evolve
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Most organic compounds contain carbon and _____. most organic compounds contain carbon and _____. phosphate nitrogen oxygen hydr
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This question can be easily confused with. During the early times, organic compound are directly associated with living beings, people, plants and animals. That is somewhat true. The definition of organic compounds are compounds that contain carbon. So, it is true that most of the compounds in our body are organic. But you may confuse it to the abundance of elements in the body, which is oxygen. However, the most abundant element, besides carbon, in organic compounds is Hydrogen. You will notice this obviously in the organic compounds like alkanes, alkenes, alkynes, carbohydrates, lipids, hormones and proteins. Their general chemical formula usually involves Carbon and Hydrogen.
4 0
3 years ago
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Benzoic acid is a natural fungicide that naturally occurs in many fruits and berries. The sodium salt of benzoic acid, sodium be
AlexFokin [52]

Answer:

a. pH = 2.52

b. pH = 8.67

c. pH = 12.83

Explanation:

The equation of the titration between the benzoic acid and NaOH is:

C₆H₅CO₂H + OH⁻ ⇄ C₆H₅CO₂⁻ + H₂O    (1)

a. To find the pH after the addition of 20.0 mL of NaOH we need to find the number of moles of C₆H₅CO₂H and NaOH:

\eta_{NaOH} = C*V = 0.250 M*0.020 L = 5.00 \cdot 10^{-3} moles

\eta_{C_{6}H_{5}CO_{2}H}i = C*V = 0.300 M*0.050 L = 0.015 moles  

From the reaction between the benzoic acid and NaOH we have the following number of moles of benzoic acid remaining:

\eta_{C_{6}H_{5}CO_{2}H} = \eta_{C_{6}H_{5}CO_{2}H}i - \eta_{NaOH} = 0.015 moles - 5.00 \cdot 10^{-3} moles = 0.01 moles

The concentration of benzoic acid is:

C = \frac{\eta}{V} = \frac{0.01 moles}{(0.020 + 0.050) L} = 0.14 M

Now, from the dissociation equilibrium of benzoic acid we have:

C₆H₅CO₂H + H₂O ⇄ C₆H₅CO₂⁻ + H₃O⁺  

0.14 - x                            x                x

Ka = \frac{[C_{6}H_{5}CO_{2}^{-}][H_{3}O^{+}]}{[C_{6}H_{5}CO_{2}H]}

Ka = \frac{x*x}{0.14 - x}

6.5 \cdot 10^{-5}*(0.14 - x) - x^{2} = 0   (2)  

By solving equation (2) for x we have:          

x = 0.0030 = [C₆H₅CO₂⁻] = [H₃O⁺]

Finally, the pH is:

pH = -log([H_{3}O^{+}]) = -log (0.0030) = 2.52

b. At the equivalence point, the benzoic acid has been converted to its conjugate base for the reaction with NaOH so, the equilibrium equation is:

C₆H₅CO₂⁻ + H₂O  ⇄  C₆H₅CO₂H + OH⁻     (3)

The number of moles of C₆H₅CO₂⁻ is:

\eta_{C_{6}H_{5}CO_{2}^{-}} = \eta_{C_{6}H_{5}CO_{2}H}i = 0.015 moles

The volume of NaOH added is:

V = \frac{\eta}{C} = \frac{0.015 moles}{0.250 M} = 0.060 L

The concentration of C₆H₅CO₂⁻ is:

C = \frac{\eta}{V} = \frac{0.015 moles}{(0.060 L + 0.050 L)} = 0.14 M

From the equilibrium of equation (3) we have:

C₆H₅CO₂⁻ + H₂O  ⇄  C₆H₅CO₂H + OH⁻  

0.14 - x                              x               x

Kb = \frac{[C_{6}H_{5}CO_{2}H][OH^{-}]}{[C_{6}H_{5}CO_{2}^{-}]}

(\frac{Kw}{Ka})*(0.14 - x) - x^{2} = 0

(\frac{1.00 \cdot 10^{-14}}{6.5 \cdot 10^{-5}})*(0.14 - x) - x^{2} = 0

By solving the equation above for x, we have:

x = 4.64x10⁻⁶ = [C₆H₅CO₂H] = [OH⁻]

The pH is:

pOH = -log[OH^{-}] = -log(4.64 \cdot 10^{-6}) = 5.33

pH = 14 - pOH = 14 - 5.33 = 8.67

     

c. To find the pH after the addition of 100 mL of NaOH we need to find the number of moles of NaOH:

\eta_{NaOH}i = C*V = 0.250 M*0.100 L = 0.025 moles

From the reaction between the benzoic acid and NaOH we have the following number of moles remaining:                              

\eta_{NaOH} = \eta_{NaOH}i - \eta_{C_{6}H_{5}CO_{2}H} = 0.025 moles - 0.015 moles = 0.010 moles                          

The concentration of NaOH is:

C = \frac{\eta}{V} = \frac{0.010 moles}{0.100 L + 0.050 L} = 0.067 M

Therefore, the pH is given by this excess of NaOH:         

pOH = -log([OH^{-}]) = -log(0.067) = 1.17

pH = 14 - pOH = 12.83

I hope it helps you!    

4 0
3 years ago
If 0.959J of heat is added to 0.88g of water, how much will its temperature increase
ss7ja [257]

Answer:

0.260 Celsius

Explanation:

q =c x m x (T2-T1)

c - specific heat of water 4.186 J/g.C

T2-T1 = q /(c x m) = 0.959 /(4.186 x 0.88) = 0.959/3.68 =0.260 C

7 0
2 years ago
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