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Morgarella [4.7K]
3 years ago
11

How much work (in J) is involved in a chemical reaction if the volume decreases from 5.35 to 1.55 L against a constant pressure

of 0.829 atm?
Chemistry
1 answer:
Mrac [35]3 years ago
5 0

Answer:- work = 319 J

Solution:- The volume of the gas decreases from 5.35 L to 1.55 L.

\Delta V=1.55L-5.35L  = -3.80 L

external pressure is given as 0.829 atm.

w=-P_e_x_t\Delta V

where w is representing work.

Let's plug in the values and calculate pressure-volume work:

w=-0.829atm(-3.80L)

w = 3.15 atm.L

We need to convert atm.L to J.

1 atm.L = 101.325 J

So, 3.15atm.L(\frac{101.325J}{1atm.L})

= 319 J

So, 319 J of work is involved in a chemical reaction. Positive work means the work is done on the system.

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A 100.0 mL solution containing 0.864 g of maleic acid (MW=116.072 g/mol) is titrated with 0.276 M KOH. Calculate the pH of the s
Lilit [14]

Answer:

pH = 1.32

Explanation:

                 H₂M + KOH ------------------------ HM⁻ + H₂O + K⁺

This problem involves a weak diprotic acid which we can solve by realizing they amount  to buffer solutions.  In the first  deprotonation if all the acid is not consumed we will have an equilibrium of a wak acid and its weak conjugate base. Lets see:

So first calculate the moles reacted and produced:

n H₂M = 0.864 g/mol x 1 mol/ 116.072 g  =  0.074 mol H₂M

54 mL x  1L / 1000 mL x 0. 0.276 moles/L = 0.015 mol KOH

it is clear that the maleic acid will not be completely consumed, hence treat it as an equilibrium problem of a buffer solution.

moles H₂M left = 0.074 - 0.015 = 0.059

moles HM⁻ produced = 0.015

Using the Henderson - Hasselbach equation to solve for pH:

ph = pKₐ + log ( HM⁻/ HA) = 1.92 + log ( 0.015 / 0.059) = 1.325

Notes: In the HH equation we used the moles of the species since the volume is the same and they will cancel out in the quotient.

For polyprotic acids the second or third deprotonation contribution to the pH when there is still unreacted acid ( Maleic in this case) unreacted.

           

3 0
3 years ago
1. During an endothermic chemical reaction, a gas is consumed and a liquid produced.
tino4ka555 [31]
1. No
2.No
I hope this helps:)
8 0
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The ionic radius for Na+ is 0.097 ηm and for Cl- is 0.181 ηm, the absolute value of the charge for each ion is 1.6x10-19 C, ε_o=
Vanyuwa [196]

Answer:

B = (2.953 × 10⁻⁹⁵) N.m⁹

Explanation:

At equilibrium, where the distance between the two ions (ro) is the sum of their ionic radii, the force between the two ions is zero.

That is,

Fa + Fr = 0

Fa = - Fr

Fa = (|q₁q₂|)/(4πε₀r²)

Fr = -B/(r^n) but n = 9

Fr = -B/r⁹

(|q₁q₂|)/(4πε₀r²) = (B/r⁹)

|q₁| = |q₂| = (1.6 × 10⁻¹⁹) C

(1/4πε₀) = k = (8.99 × 10⁹) Nm²/C²

r = 0.097 + 0.181 = 0.278 nm = (2.78 × 10⁻¹⁰) m

(k|q₁q₂|)/(r²) = (B/r⁹)

(k × |q₁q₂|) = (B/r⁷)

B = (k × |q₁q₂| × r⁷)

B = [8.99 × 10⁹ × 1.6 × 10⁻¹⁹ × 1.6 × 10⁻¹⁹ × (2.78 × 10⁻¹⁰)⁷]

B = (2.953 × 10⁻⁹⁵) N.m⁹

6 0
3 years ago
How many moles of water are produced when 5 moles of hydrogen gas react with 2 moles of oxygen gas?
ASHA 777 [7]
How many moles of water at produced when 5 moles of hydrogen gas react with 2 moles of oxygen gas the answer is D
5 0
3 years ago
HELP a #QUEEN out pls??
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Answer:

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Explanation:

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__5___SiO2 + ___2___CaC2 → __5___Si + ____2___CaO + __4___CO2

4 0
2 years ago
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