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Morgarella [4.7K]
3 years ago
11

How much work (in J) is involved in a chemical reaction if the volume decreases from 5.35 to 1.55 L against a constant pressure

of 0.829 atm?
Chemistry
1 answer:
Mrac [35]3 years ago
5 0

Answer:- work = 319 J

Solution:- The volume of the gas decreases from 5.35 L to 1.55 L.

\Delta V=1.55L-5.35L  = -3.80 L

external pressure is given as 0.829 atm.

w=-P_e_x_t\Delta V

where w is representing work.

Let's plug in the values and calculate pressure-volume work:

w=-0.829atm(-3.80L)

w = 3.15 atm.L

We need to convert atm.L to J.

1 atm.L = 101.325 J

So, 3.15atm.L(\frac{101.325J}{1atm.L})

= 319 J

So, 319 J of work is involved in a chemical reaction. Positive work means the work is done on the system.

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How many grams of calcium phosphate (Ca3(PO4)2) re theoretically produced if we start with 3.40 moles of Ca(NO3)2 and 2.40moles
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1) Balance the chemical equation.

3Ca(NO_3)_2+2Li_3PO_4\rightarrow6LiNO_3+Ca_3(PO_4)_2

2) List the known and unknown quantities.

Reactant 1: Ca(NO3)2.

Amount of substance: 3.40 mol.

Reactant 2: Li3PO4.

Amount of substance: 2.40 mol.

Product: Ca3(PO4)2

Mass: unknown.

3) Which is the limiting reactant?

<em>3.1-How many moles of Li3PO4 do we need to use all of the Ca(NO3)2?</em>

The molar ratio between Li3PO4 and Ca(NO3)2 is 2 mol Li3PO4: 3 mol Ca(NO3)2.

mol\text{ }Li_3PO_4=3.40\text{ }mol\text{ }Ca(NO_3)_2*\frac{2\text{ }mol\text{ }Li_3PO_4}{3\text{ }mol\text{ }Ca(NO_3)_2}=2.2667\text{ }mol\text{ }Li_3PO_4

<em>We need 2.2667 mol Li3PO4 and we have 2.40 mol Li3PO4. We have enough Li3PO4. </em>This is the excess reactant.

<em>3.2-How many moles of Ca(NO3)2 do we need to use all of the Li3PO4?</em>

The molar ratio between Li3PO4 and Ca(NO3)2 is 2 mol Li3PO4: 3 mol Ca(NO3)2.

mol\text{ }Ca(NO_3)_2=2.40\text{ }mol\text{ }Li_3PO_4*\frac{3\text{ }mol\text{ }Ca(NO_3)_2}{2\text{ }mol\text{ }Li_3PO_4}=3.60\text{ }mol\text{ }Ca(NO_3)_2

<em>We need 3.60 mol Ca(NO3)2 and we have 3.40 mol Ca(NO3)2. We do not have enough Ca(NO3)2. </em>This is the limiting reactant.

4) Moles of Ca3(PO4)2 produced from the limiting reactant.

We have 3.40 mol Ca(NO3)2 of the limiting reactant.

The molar ratio between Ca(NO3)2 and Ca3(PO4)2 is 3 mol Ca(NO3)2: 1 mol Ca3(PO4)2.

mol\text{ }Ca_3(PO_4)_2=3.40\text{ }mol\text{ }Ca(NO_3)_2*\frac{1\text{ }mol\text{ }Ca_3(PO_4)_2}{3\text{ }mol\text{ }Ca(NO_3)_2}=1.1313\text{ }mol\text{ }Ca_3(PO_4)_2

5) Mass of Ca3(PO4)2 produced.

The molar mass of Ca3(PO4)2 is 310.1767 g/mol.

g\text{ }Ca_3(PO_4)_2=1.1333\text{ }mol\text{ }Ca_3(PO_4)_2*\frac{310.1767\text{ }g\text{ }Ca_3(PO_4)_2}{1\text{ }mol\text{ }Ca_3(PO_4)_2}g\text{ }Ca_3(PO_4)_2=351.526\text{ }g\text{ }Ca_3(PO_4)_2

<em>The mass of Ca3(PO4)2 produced is</em> 351 g Ca3(PO4)2.

Option D.

.

8 0
1 year ago
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