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mestny [16]
3 years ago
13

The rate of disappearance of HBr in the gas phase reaction 2HBr(g) → H2 (g) I2 (g) is 0.190 M s-1 at 150°C. The rate of appearan

ce of H2 is ________ M s-1. Group of answer choices
Chemistry
1 answer:
Sunny_sXe [5.5K]3 years ago
3 0

Answer:

The rate of appearance of hydrogen gas is 0.095 M/s.

Explanation:

Rate of the reaction is the change in concentration of of any one of the reactants or products per unit time.

2HBr(g)\rightarrow H_2 (g) I_2 (g)

Given:

The rate of disappearance of HBr = -\frac{d[HBr]}{dt}=0.190 M/s

Rate of the reaction is given by:

R=-\frac{1}{2}\frac{d[HBr]}{dt}=\frac{1}{1}\frac{d[H_2]}{dt}

R=-\frac{1}{2}\frac{d[HBr]}{dt}=\frac{1}{2}\times 0.190 M/s=0.095 M/s

Rate of appearance of the hydrogen gas:

\frac{d[H_2]}{dt}=R =0.095 M/s

The rate of appearance of hydrogen gas is 0.095 M/s.

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The Michaelis constant for pancreatic lipase is 5 mM. At 60 C, lipase is subject to deactivation with a half-life of 8 min. Fat
Dmitriy789 [7]

Explanation:

According to the given data, we will calculate the following.

 Half life of lipase t_{1/2} = 8 min x 60 s/min

                                       = 480 s

Rate constant for first order reaction is as follows.

         k_{d} = \frac{0.6932}{480}

                        = 1.44 \times 10^{-3}s^{-1}


Initial fat concentration S_{o} = 45 mol/m^{3}

                                                = 45 mmol/L

Rate of hydrolysis V_m_{o} = 0.07 mmol/L/s

Conversion X = 0.80

Final concentration (S) = S_{o} (1 - X)

                                      = 45 (1 - 0.80)

                                      = 9 mol/m^{3}

or,                                  = 9 mmol/L

It is given that K_{m} = 5mmol/L

Therefore, time taken will be calculated as follows.

                    t = -\frac{1}{K_{d}}ln[1 - \frac{K_{d}}{V}{K_{M} ln (\frac{S_{o}}{S}) + (S_{o} - S)]

Now, putting the given values into the above formula as follows.

            t = -\frac{1}{K_{d}}ln[1 - \frac{K_{d}}{V}{K_{M} ln (\frac{S_{o}}{S}) + (S_{o} - S)]  

             = -\frac{1}{1.44 \times 10^{-3}s^{-1}}ln[1 - \frac{1.44 \times 10^{-3}s^{-1}}{0.07 mmol/L/s
}{K_{M} ln (\frac{45 mmol/L
}{9 mmol/L
}) + (45 mmol/L - 9 mmol/L
)]

              = 1642.83 s \times \frac{1 min}{60 sec}

              = 27.38 min

Therefore, we can conclude that time taken by the enzyme to hydrolyse 80% of the fat present is 27.38 min.

6 0
3 years ago
An ideal gas contained in a piston-cylinder assembly is compressed isothermally in an internally reversible process.
Tju [1.3M]

Answer:

a) \Delta S

b) entropy of the sistem equal to a), entropy of the universe grater than a).

Explanation:

a) The change of entropy for a reversible process:

\delta S=\frac{\delta Q}{T}

\Delta S=\frac{Q}{T}

The energy balance:

\delta U=[tex]\delta Q- \delta W

If the process is isothermical the U doesn't change:

0=[tex]\delta Q- \delta W

\delta Q= \delta W

Q= W

The work:

W=\int_{V1}^{V2}P*dV

If it is an ideal gas:

P=\frac{n*R*T}{V}

W=\int_{V1}^{V2}\frac{n*R*T}{V}*dV

Solving:

W=n*R*T*ln(V2/V1)

Replacing:

\Delta S=\frac{n*R*T*ln(V2/V1)}{T}

\Delta S=n*R*ln(V2/V1)}

Given that it's a compression: V2<V1 and ln(V2/V1)<0. So:

\Delta S

b) The entropy change of the sistem will be equal to the calculated in a), but the change of entropy of the universe will be 0 in a) (reversible process) and in b) has to be positive given that it is an irreversible process.

7 0
3 years ago
A sample of neon initially has a volume of 2.80 L at 23 degrees Celsius. What is final temperature, in degrees Celsius, is neede
finlep [7]

The relation between the volume and the temperature of the gas is given by Charles's law. The final temperature of the gas at 0.75 liters is -193.8°C.

<h3>What is Charles's law?</h3>

Charles's law was derived from the ideal gas equation and is used to state the relationship between the temperature and the volume of the gas. With a decrease in volume the temperature decreases.

If the pressure is kept constant then with an increase in temperature the volume of the gas expands. The law is given as,

V₁ ÷ T₁ = V₂ ÷ T₂

Given,

Initial volume (V₁) = 2.80 L

Initial temperature (T₁) = 23 °C = 296.15 K

Final volume (V₂) = 0.75 L

Final temperature = T₂

Substituting the values above as:

T₂ = (V₂ × T₁) ÷ V₁

= 0.75 × 296.15 ÷ 2.80

= 79.325 K

Kelvin is converted as, 79.325K − 273.15 = -193.8°C

Therefore, the final temperature is -193.8°C.

Learn more about Charle's law, here:

brainly.com/question/16927784

#SPJ1

7 0
1 year ago
One phosphorus, three chlorine, one oxygen
4vir4ik [10]
Phosphoryl chloride :

POCl3
<span>
hope this helps!.

</span>
5 0
3 years ago
Balance the equation ___ CaCO3 -&gt; ____ CaO + ____ CO2
Degger [83]

Answer:

CaCO3 -> CaO + CO2

Explanation:

Woahhhh, did you balance it yourself just then?

3 0
2 years ago
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