
The emission spectrum of a chemical element or chemical compound is the spectrum of frequencies of electromagnetic radiation emitted due to an atom or molecule making a transition from a high energy state to a lower energy state. The photon energy of the emitted photon is equal to the energy difference between the two states. There are many possible electron transitions for each atom, and each transition has a specific energy difference. This collection of different transitions, leading to different radiated wavelengths, make up an emission spectrum. Each element's emission spectrum is unique. Therefore, spectroscopy can be used to identify elements in matter of unknown composition. Similarly, the emission spectra of molecules can be used in chemical analysis of substances.
Answer : (b) The rate law expression for the reaction is:
![\text{Rate}=k[SO_2]^2[O_2]](https://tex.z-dn.net/?f=%5Ctext%7BRate%7D%3Dk%5BSO_2%5D%5E2%5BO_2%5D)
Explanation :
Rate law : It is defined as the expression which expresses the rate of the reaction in terms of molar concentration of the reactants with each term raised to the power their stoichiometric coefficient of that reactant in the balanced chemical equation.
The general reaction is:

The general rate law expression for the reaction is:
![\text{Rate}=k[A]^a[B]^b](https://tex.z-dn.net/?f=%5Ctext%7BRate%7D%3Dk%5BA%5D%5Ea%5BB%5D%5Eb)
where,
a = order with respect to A
b = order with respect to B
R = rate law
k = rate constant
and
= concentration of A and B reactant
Now we have to determine the rate law for the given reaction.
The balanced equations will be:

In this reaction,
and
are the reactants.
The rate law expression for the reaction is:
![\text{Rate}=k[SO_2]^2[O_2]^1](https://tex.z-dn.net/?f=%5Ctext%7BRate%7D%3Dk%5BSO_2%5D%5E2%5BO_2%5D%5E1)
or,
![\text{Rate}=k[SO_2]^2[O_2]](https://tex.z-dn.net/?f=%5Ctext%7BRate%7D%3Dk%5BSO_2%5D%5E2%5BO_2%5D)
Answer:
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Explanation: