The pH of a solution is 9.02.
c(HCN) = 1.25 M; concentration of the cyanide acid
n(NaCN) = 1.37 mol; amount of the salt
V = 1.699 l; volume of the solution
c(NaCN) = 1.37 mol ÷ 1.699 l
c(NaCN) = 0.806 M; concentration of the salt
Ka = 6.2 × 10⁻¹⁰; acid constant
pKa = -logKa
pKa = - log (6.2 × 10⁻¹⁰)
pKa = 9.21
Henderson–Hasselbalch equation for the buffer solution:
pH = pKa + log(cs/ck)
pH = pKa + log(cs/ck)
pH = 9.21 + log (0.806M/1.25M)
pH = 9.21 - 0.19
pH = 9.02; potential of hydrogen
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Answer : The molar mass of the solute would be low.
Explanation :
Formula used for depression in freezing point is:
where,
= change in freezing point
= freezing point of solution
= freezing point of water
i = Van't Hoff factor
= freezing point constant
m = molality
= mass of solute
= mass of solvent
= molar mass of solute
From the formula we conclude that, when the freezing point of the solution read incorrectly that is freezing point of the solution is lower than the true freezing point then this means that change in freezing point would be high and the molar mass of the solute would be low.
Hence, the molar mass of the solute would be low.
The enthalpy for the reaction : ΔH = -132
<h3>Further explanation</h3>
Given
Reaction and the enthalpy
Required
the enthalpy
Solution
Hess Law
Reaction 1 reverse :
A + B = G + C ΔH = -277
Reactions 2 and 3 remain the same (unchanged)
C + F = A ΔH = 303
D = B + H ΔH = -158
Add up all the reactions and remove the same compound from two different sides
D + F = G + H ΔH = -132
The bathtub of water would melt the most ice because it has a larger area
