Answer:
The reaction rate of the both questions remain unchanged.
Explanation:
For question 1: The reaction 1-iodo -2- methylbutane with cyanide ion is an SN2 reaction because the Alkyl halide is a primary alkyl halide. The rate of reaction is dependent on concentration of the nucleophile and the alkyl halide at the same. For the rate of reaction to be affected (increased or decreased), the concentration of nucleophile and the alkyl halide have to be altered.
For question 2: The reaction of 2-iodo -2- methylbutane with ethanol is an SN1 reaction because the Alkyl halide is a tertiary alkyl halide. There are two-step reaction mechanism in this reaction. The first step is the rate determining step which determines the extent of the reaction and hence the rate of reaction. For the rate of reaction to be affected (increased or decreased), the concentration of the Alkyl halide alone will be altered. The rate of reaction is independent of the concentration of the nucleophile.
Answer:
1. 7 (a neutral solution)
Answer: 10-7= 0.0000001 moles per liter
2. 5.6 (unpolluted rainwater)
Answer: 10-5.6 = 0.0000025 moles per liter
3. 3.7 (first acid rain sample in North America)
Answer: 10-3.7 = 0.00020 moles per liter
The concentration of H+ in the Hubbard Brook sample is 0.00020/0.0000025, which is 80 times higher than the H+ concentration in unpolluted rainwater.
Explanation:
Explanation:
balance the equation ...HCl,Ba(OH) and BaCl2 are aqueous
know groups of the elements H 1+ ,Cl -,Ba 2+,OH-
write complete ionic eqution and eliminate spectator ions those appearing on both sides Cl and Ba
Answer:
[HF]₀ = 0.125M
Explanation:
NaOH + HF => NaF + H₂O
Adding 20ml of 0.200M NaOH into 25ml of HF solution neutralizes 0.004 mole of HF leaving 0.004 mole NaF in 0.045L with 0.001M H⁺ at pH = 3. This is 0.089M NaF and 0.001M HF remaining.
=> 45ml of solution with pH = 3 and contains 0.089M NaF from titration becomes a common ion problem.
HF ⇄ H⁺ + F⁻
C(eq) [HF] 10⁻³M 0.089M (<= soln after adding 20ml 0.200M NaOH)
Ka = [H⁺][F⁻]/[HF]₀ => [HF]₀ = [H⁺][F⁻]/Ka
[HF]₀ = (0.001)(0.089)/(7.1 x 10⁻⁴) M = 0.125M