"A <span>gas condensing to a liquid" is the one system among the following choices given in the question where the entropy is decreasing. The correct option among all the options that are given in the question is the fourth option or option "D". I hope that this is the answer that has come to your desired help.</span>
hope it helps ..............
Rate law for the given 2nd order reaction is:
Rate = k[a]2
Given data:
rate constant k = 0.150 m-1s-1
initial concentration, [a] = 0.250 M
reaction time, t = 5.00 min = 5.00 min * 60 s/s = 300 s
To determine:
Concentration at time t = 300 s i.e. ![[a]_{t}](https://tex.z-dn.net/?f=%5Ba%5D_%7Bt%7D)
Calculations:
The second order rate equation is:
![1/[a]_{t} = kt +1/[a]](https://tex.z-dn.net/?f=1%2F%5Ba%5D_%7Bt%7D%20%3D%20kt%20%2B1%2F%5Ba%5D)
substituting for k,t and [a] we get:
1/[a]t = 0.150 M-1s-1 * 300 s + 1/[0.250]M
1/[a]t = 49 M-1
[a]t = 1/49 M-1 = 0.0204 M
Hence the concentration of 'a' after t = 5min is 0.020 M
There are 3,500 milliseconds in 3.5 seconds. Hope this helps!
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