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Answer:
According to Le-chatelier principle, equilibrium will shift towards left to minimize concentration of
and keep same equilibrium constant
Explanation:
In this buffer following equilibrium exists -

So,
is involved in the above equilibrium.
When a strong base is added to this buffer, then concentration of
increases. Hence, according to Le-chatelier principle, above equilibrium will shift towards left to minimize concentration of
and keep same equilibrium constant.
Therefore excess amount of
combines with
to produce ammonia and water. So, effect of addition of strong base on pH of buffer gets minimized.
Missing question: What is the rate constant for the reaction?
<span>[RS2](mol L-1) Rate (mol/(L·s))
0.150 0.0394
0.250 0.109
0.350 0.214
0.500 0.438</span>
Chemical reaction: 3RS₂ → 3R + 6S.
Compare second and fourth experiment, when concentration is doubled, rate of concentration is increaced by four. So rate is:
rate = k·[RS₂]².
k = 0,438 ÷ (0,500)².
k = 1,75 L/mol·s.
It's simple, just follow my steps.
1º - in 1 L we have

of

2º - let's find the number of moles.



3º - The concentration will be

But we have this reaction

This concentration will be the concentration of

![K_{sp}=\frac{[Ba^{2+}][CO_3^{2-}]}{[BaCO_3]}](https://tex.z-dn.net/?f=K_%7Bsp%7D%3D%5Cfrac%7B%5BBa%5E%7B2%2B%7D%5D%5BCO_3%5E%7B2-%7D%5D%7D%7B%5BBaCO_3%5D%7D)
considering
![[BaCO_3]=1~mol/L](https://tex.z-dn.net/?f=%5BBaCO_3%5D%3D1~mol%2FL)
![K_{sp}=[Ba^{2+}][CO_3^{2-}]](https://tex.z-dn.net/?f=K_%7Bsp%7D%3D%5BBa%5E%7B2%2B%7D%5D%5BCO_3%5E%7B2-%7D%5D)
and
![[Ba^{2+}]=[CO_3^{2-}]=5.07\times10^{-5}~mol/L](https://tex.z-dn.net/?f=%5BBa%5E%7B2%2B%7D%5D%3D%5BCO_3%5E%7B2-%7D%5D%3D5.07%5Ctimes10%5E%7B-5%7D~mol%2FL)
We can replace it


Therefore the

is: