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2 years ago

14

When a strong acid is titrated with a weak base, the pH at the equivalence point Multiple Choice is greater than 7.0. is equal t

o 7.0. is less than 7.0. is equal to the pKa of the conjugate acid. is equal to the pKb of the base.

1 answer:

expeople1 [14]2 years ago

7 0

Answer: C) Is less than 7.0

Explanation:

For a strong acid and weak base titration, pH < 7

For a strong acid and strong base titration pH = 7

For a strong base and weak acid titration pH > 7

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Consider the reaction

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Answer :

(a) The average rate will be:

$\frac{d[Br_2]}{dt}=9.36\times 10^{-5}M/s$

(b) The average rate will be:

$\frac{d[H^+]}{dt}=1.87\times 10^{-4}M/s$

Explanation :

The general rate of reaction is,

$aA+bB\rightarrow cC+dD$

Rate of reaction : It is defined as the change in the concentration of any one of the reactants or products per unit time.

The expression for rate of reaction will be :

$\text{Rate of disappearance of A}=-\frac{1}{a}\frac{d[A]}{dt}$

$\text{Rate of disappearance of B}=-\frac{1}{b}\frac{d[B]}{dt}$

$\text{Rate of formation of C}=+\frac{1}{c}\frac{d[C]}{dt}$

$\text{Rate of formation of D}=+\frac{1}{d}\frac{d[D]}{dt}$

$Rate=-\frac{1}{a}\frac{d[A]}{dt}=-\frac{1}{b}\frac{d[B]}{dt}=+\frac{1}{c}\frac{d[C]}{dt}=+\frac{1}{d}\frac{d[D]}{dt}$

From this we conclude that,

In the rate of reaction, A and B are the reactants and C and D are the products.

a, b, c and d are the stoichiometric coefficient of A, B, C and D respectively.

The negative sign along with the reactant terms is used simply to show that the concentration of the reactant is decreasing and positive sign along with the product terms is used simply to show that the concentration of the product is increasing.

The given rate of reaction is,

$5Br^-(aq)+BrO_3^-(aq)+6H^+(aq)\rightarrow 3Br_2(aq)+3H_2O(l)$

The expression for rate of reaction :

$\text{Rate of disappearance of }Br^-=-\frac{1}{5}\frac{d[Br^-]}{dt}$

$\text{Rate of disappearance of }BrO_3^-=-\frac{d[BrO_3^-]}{dt}$

$\text{Rate of disappearance of }H^+=-\frac{1}{6}\frac{d[H^+]}{dt}$

$\text{Rate of formation of }Br_2=+\frac{1}{3}\frac{d[Br_2]}{dt}$

$\text{Rate of formation of }H_2O=+\frac{1}{3}\frac{d[H_2O]}{dt}$

Thus, the rate of reaction will be:

$\text{Rate of reaction}=-\frac{1}{5}\frac{d[Br^-]}{dt}=-\frac{d[BrO_3^-]}{dt}=-\frac{1}{6}\frac{d[H^+]}{dt}=+\frac{1}{3}\frac{d[Br_2]}{dt}=+\frac{1}{3}\frac{d[H_2O]}{dt}$

<u>Part (a) :</u>

<u>Given:</u>

$\frac{1}{5}\frac{d[Br^-]}{dt}=1.56\times 10^{-4}M/s$

As,

$-\frac{1}{5}\frac{d[Br^-]}{dt}=+\frac{1}{3}\frac{d[Br_2]}{dt}$

and,

$\frac{d[Br_2]}{dt}=\frac{3}{5}\frac{d[Br^-]}{dt}$

$\frac{d[Br_2]}{dt}=\frac{3}{5}\times 1.56\times 10^{-4}M/s$

$\frac{d[Br_2]}{dt}=9.36\times 10^{-5}M/s$

<u>Part (b) :</u>

<u>Given:</u>

$\frac{1}{5}\frac{d[Br^-]}{dt}=1.56\times 10^{-4}M/s$

As,

$-\frac{1}{5}\frac{d[Br^-]}{dt}=-\frac{1}{6}\frac{d[H^+]}{dt}$

and,

$-\frac{1}{6}\frac{d[H^+]}{dt}=\frac{3}{5}\frac{d[Br^-]}{dt}$

$\frac{d[H^+]}{dt}=\frac{6}{5}\times 1.56\times 10^{-4}M/s$

$\frac{d[H^+]}{dt}=1.87\times 10^{-4}M/s$

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Mathematically, it can be written as:

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where

p1 is the initial pressure

T1 is the initial temperature (in Kelvin)

p2 is the final pressure

T2 is the final temperature (in Kelvin)

Therefore, in order to solve for one of the 4 variables, the following steps must be adopted:

A. List your knowns and unknowns.

B. Convert temperature to kelvin.

D. Solve for the unknown.

While the following step is not needed:

C. Plug the unknowns into the ideal gas law formula.

Because we do not need to use the ideal gas law formula.

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masya89 [10]

Answer:

On edge nuity, it is 79.

Explanation:

Please read the explanation.

Since u have no coefficients, this problem is super easy.

You just add your products, 115.5+69.91 = 185.41

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It's really easy. Once u understand it, you can do any problem like this. If there is coefficients, just multiply the coefficient by the amount given to you in the problem.

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