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emmainna [20.7K]
3 years ago
15

. Write the two resonance hybrids for the carbocation that would be formed by protonation at C-1 of 2-methyl-1,3-pentadiene. Wit

hout doing a calculation, would you expect C-2 or C-4 (the two end carbons of the allylic cation) to have the most positive charge on it
Chemistry
1 answer:
never [62]3 years ago
8 0

Answer:

Answer is explained in the explanation section below.

Explanation:

This question is requires the diagram, which I have drawn and it is attached in the attachment below. Please for this answer, refer to the diagram attached in the attachment below.

Referring to the diagram, attached. As we know that, Allylic secondary carbocations are more stable than Allylic tertiary carbocations.

Hence,

C2 will have a more positive charge since a tertiary carbocation (C2) is more stable than a secondary carbocation (C4). Therefore, the resonance structure will favor the positive charge at C2.

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I need help with these
Dafna11 [192]
Can you elaborate this a little more?
8 0
3 years ago
A solution containing 20.0 g of an unknown liquid and 110.0 g water has a freezing point of .32 °C. Given Kf 1.86°C/m for water,
hjlf

Answer:

A. 256

Explanation:

In a solution where a liquid is the sovent, we'll use the van't Hoff factor, which is the ratio between the number of moles of particles produced in solution and the number of moles of solute dissolved, will be equal to 1.

ΔTemp.f = i * Kf * b

where,

ΔTemp.f = the freezing-point depression;

i = the van't Hoff factor

Kf = the cryoscopic constant of the solvent;

b = the molality of the solution.

So the freezing-point depression by definition is the difference between the the freezing point of the pure solvent and the freesing point of the solution.

Mathematically,

ΔTemp.f = Temp.f° - Temp.f

where,

Temp.f° = the freezing point of the pure solvent.

Temp.f = the freezin point of the solution.

Freezing point of pure water = 0°C

ΔTemp.f = 0 - (-1.32)

= 1.32°C

i = 1,

Kf = 1.86 °Ckg/mol

Solving for the molality, b = ΔTemp.f/( i * Kf)

= 1.32/(1*1.86)

= 0.71 mol/kg

Converting from mol/kg to mol/g,

0.71 mol/kg * 1kg/1000g

= 0.00071 mol/g.

Mass of solvent = 110g

Number of moles = mass * molality

= 0.00071 * 110

= 0.078 mol.

To calculate molar mass,

Molar mass (g/mol) = mass/number of moles

Mass of solute (liquid) = 20g

Molar mass = 20/0.078

= 256.2 g/mol

4 0
3 years ago
Water is made of polar molecules, and oil is made of nonpolar molecules. Based on your observations, which molecules attract eac
victus00 [196]

Based on observation of polar and non-polar molecules, polar molecules would attract each other more strongly.

<h3>What are polar and non-polar molecules?</h3>

Polar molecules are those molecules that can ionize or dissociate into their respective positive and negative ions when in an aqueous solution.

Nonpolar molecules, on the other hand, are not ionic i.e. not dissociating into ions when dissolved in water.

Polar molecules like water (H2O) contains an uneven distribution of cations (+) and anions (-), hence, would be more attracted to one another than nonpolar molecules that have an even distribution of ions.

Learn more about polarity at: brainly.com/question/16106487

#SPJ1

3 0
2 years ago
What is the conversion of 12.044x10^23 to a gram
postnew [5]

Answer:

8.4g

Explanation:

6 0
3 years ago
10. A small helium tank claims to be able to fill 30 balloons to a volume of 3.15 L
Sindrei [870]

Taking into account the Boyle's law, 3.377 L of helium the tank will be able to  produce at a pressure of 94.2 kPa.

The gas laws are a set of chemical and physical laws that allow determining the behavior of gases in a closed system. The parameters evaluated in these laws are pressure, volume, temperature, and moles.

Boyle's law is one of the gas laws that relates the volume and pressure of a certain quantity of gas kept at constant temperature.

This law states that the pressure of a gas in a closed container is inversely proportional to the volume of the container, when the temperature is constant. That is, if the pressure increases, the volume decreases; while if the pressure decreases, the volume increases.

Mathematically, Boyle's law states that the product of pressure and volume is constant:

P×V= k

Studying two different states, an initial state 1 and a final state 2, it is satisfied:

P1× V1= P2×V2

In this case, you know:

  • P1= 101 kPa
  • V1= 3.15 L
  • P2= 94.2 kPa
  • V2= ?

Replacing in Boyle's law:

101 kPa× 3.15 L= 94.2 kPa× V2

Solving:

V2=\frac{101 kPa x3.15 L}{94.2 kPa}

<u><em>V2= 3.377 L</em></u>

In summary, 3.377 L of helium the tank will be able to  produce at a pressure of 94.2 kPa.

Learn more:

brainly.com/question/4147359?referrer=searchResults

7 0
3 years ago
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