B. elements and compounds
Solubility is the maximum amount of a substance that will dissolve in a given amount of solvent at a specific temperature. There are two direct factors that affect solubility: temperature and pressure. Temperature affects the solubility of both solids and gases, but pressure only affects the solubility of gases.
(a) One form of the Clausius-Clapeyron equation is
ln(P₂/P₁) = (ΔHv/R) * (1/T₁ - 1/T₂); where in this case:
Solving for ΔHv:
- ΔHv = R * ln(P₂/P₁) / (1/T₁ - 1/T₂)
- ΔHv = 8.31 J/molK * ln(5.3/1.3) / (1/358.96 - 1/392.46)
(b) <em>Normal boiling point means</em> that P = 1 atm = 101.325 kPa. We use the same formula, using the same values for P₁ and T₁, and replacing P₂ with atmosferic pressure, <u>solving for T₂</u>:
- ln(P₂/P₁) = (ΔHv/R) * (1/T₁ - 1/T₂)
- 1/T₂ = 1/T₁ - [ ln(P₂/P₁) / (ΔHv/R) ]
- 1/T₂ = 1/358.96 K - [ ln(101.325/1.3) / (49111.12/8.31) ]
(c)<em> The enthalpy of vaporization</em> was calculated in part (a), and it does not vary depending on temperature, meaning <u>that at the boiling point the enthalpy of vaporization ΔHv is still 49111.12 J/molK</u>.
Answer:
Genetic equilibrium is the state in which allele frequencies do
not change in a generation over generation.
Explanation:
Genetic equilibrium can be described as a situation which arises when a certain allele or genotype remains constant for a species generation over generations. Genetic equilibrium can be maintained if no external factors like mutations affect the population of the species. The phenomenon of natural selection and evolution need to be stopped if a genetic equilibrium is to be maintained. Hardy-Weinberg theorem is the mathematical depiction of genetic equilibrium.
