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den301095 [7]
3 years ago
9

SELECT ALL THAT APPLY. Which of the following statements about Charles's law are true?

Chemistry
2 answers:
Serjik [45]3 years ago
7 0
A. Real gases may be expected to deviate from Charles's law at high pressures.

C. Real gases may be expected to deviate from Charles's law near the liquefaction temperature.
Ludmilka [50]3 years ago
3 0

Answer is:

A. Real gases may be expected to deviate from Charles's law at high pressures.

C. Real gases may be expected to deviate from Charles's law near the liquefaction temperature.

At high pressure gas molecules are close to one another and near the liqueffaction temperature energy is very low.

Charles' Law (The Temperature-Volume Law) - the volume of a given amount of gas held at constant pressure is directly proportional to the Kelvin temperature:  

V₁/T₁ = V₂/T₂.  

When temperature goes down, the volume also goes down.


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Sodium tert-butoxide (NaOC(CH3)3) is classified as bulky and acts as Bronsted Lowry base in the reaction. It is reacted with 2-c
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Answer:but-1-ene

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Kindly refer the attachment for complete reaction and products.

Sodium tert-butoxide is a bulky base and hence cannot approach the substrate 2-chlorobutane from the more substituted end and hence major product formed here would not be following zaitsev rule of elimination reaction.

Sodium tert-butoxide would approach from the less hindered side that is through the primary centre and hence would lead to the formation of 1-butene .The major product formed in this reaction would be 1-butene .

As the mechanism of the reaction is E-2 so it will be a concerted mechanism and as sodium tert-butoxide will start abstracting the primary hydrogen through the less hindered side simultaneously chlorine will start leaving. As the steric repulsion in this case is less hence the transition state is relatively stabilised and leads to the formation of a kinetic product 1-butene.

Kinetic product are formed when reactions are dependent upon rate and not on thermodynamical stability.

2-butene is more thermodynamically6 stable as compared to 1-butene  

The major product formed does not follow the zaitsev rule of forming a more substituted alkene as sodium tert-butoxide cannot approach to abstract the secondary proton due to steric hindrance.

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3 years ago
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