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3 years ago

Please help me with this, thank you so much

Chemistry

1 answer:

Basile [38]3 years ago

7 0

I can’t answer the exact thing, but I know how to do it. One of the nitrogen bases always pairs with a different one, so once you know what pairs with what you just write it down. If you need more help just ask :) tip: one base will only join with a different one. One won’t join to multiple (from what I know as of now)

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1. The solubility of lead(II) chloride at some high temperature is 3.1 x 10-2 M. Find the Ksp of PbCl2 at this temperature.

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Answer:

1) The solubility product of the lead(II) chloride is $1.2\times 10^{-4}$ .

2) The solubility of the aluminium hydroxide is $1.6\times 10^{-10} M$ .

3)The given statement is false.

Explanation:

Solubility of lead chloride = $S=3.1\times 10^-2M$

$PbCl_2(aq)\rightleftharpoons Pb^{2+}(aq)+2Cl^-(aq)$

S 2S

The solubility product of the lead(II) chloride = $K_{sp}$

$K_{sp}=[Pb^{2+}][Cl^-]^2$

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The solubility product of the lead(II) chloride is $1.2\times 10^{-4}$ .

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$Molarity=\frac{Moles}{Volume (L)}$

Mass of NaCl= 3.5 mg = 0.0035 g

1 mg = 0.001 g

Moles of NaCl = $\frac{0.0035 g}{58.5 g/mol}=6.0\times 10^{-5} mol$

Volume of the solution = 0.250 L

$[NaCl]=\frac{6.0\times 10^{-5} mol}{0.250 L}=0.00024 M$

1 mole of NaCl gives 1 mole of sodium ion and 1 mole of chloride ions.

$[Cl^-]=[NaCl]=0.00024 M$

Moles of lead (II) nitrate = n

Volume of the solution = 0.250 L

Molarity lead(II) nitrate = 0.12 M

$n=0.12 M]\times 0.250 L=0.030 mol$

1 mole of lead nitrate gives 1 mole of lead (II) ion and 2 moles of nitrate ions.

$[Pb^{2+}]=[Pb(NO_2)_3]=0.030 M$

$PbCl_2(aq)\rightleftharpoons Pb^{2+}(aq)+2Cl^-(aq)$

Solubility of lead(II) chloride = $K_{sp}=1.2\times 10^{-4}$

Ionic product of the lead chloride in solution :

$Q_i=[Pb^{2+}][Cl^-]^2=0.030 M\times (0.00024 M)^2=1.7\times 10^{-9}$

$Q_i$ ( no precipitation)

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