Antimony is a chemical element with symbol Sb (from Latin: stibium) and atomic number 51. A lustrous gray metalloid, it is found in nature mainly as the sulfide mineral stibnite (Sb2S3). Antimony compounds have been known since ancient times and were powdered for use as medicine and cosmetics, often known by the Arabic name, kohl.
At equivalence there is no more HA and no more NaOH, for this particular reaction. So that means we have a beaker of NaA and H2O. The H2O contributes 1 x 10-7 M hydrogen ion and hydroxide ion. But NaA is completely soluble because group 1 ion compounds are always soluble. So NaA breaks apart in water and it just so happens to be in water. So now NaA is broken up. The Na+ doesn't change the pH but the A- does change the pH. Remember that the A anion is from a weak acid. That means it will easily attract a hydrogen ion if one is available. What do you know? The A anion is in a beaker of H+ ions! So the A- will attract H+ and become HA. When this happens, it leaves OH-, creating a basic solution, as shown below.
If Ka for HBrO is 2. 8×10^−9 at 25°C, then the value of Kb for BrO− at 25°C is 3.5× 10^(-6).
<h3>
What is base dissociation constant?
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The base dissociation constant (Kb) is defined as the measurement of the ions which base can dissociate or dissolve in the aqueous solution. The greater the value of base dissociation constant greater will be its basicity an strength.
The dissociation reaction of hydrogen cyanide can be given as
HCN --- (H+) + (CN-)
Given,
The value of Ka for HCN is 2.8× 10^(-9)
The correlation between base dissociation constant and acid dissociation constant is
Kw = Ka × Kb
Kw = 10^(-14)
Substituting values of Ka and Kw,
Kb = 10^(-14) /{2.8×10^(-9) }
= 3.5× 10^(-6)
Thus, we find that if Ka for HBrO is 2. 8×10^−9 at 25°C, then the value of Kb for BrO− at 25°C is 3.5× 10^(-6).
DISCLAIMER: The above question have mistake. The correct question is given as
Question:
Given that Ka for HBrO is 2. 8×10^−9 at 25°C. What is the value of Kb for BrO− at 25°C?
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The equation that is correct for coffee-cup calorimeter is q reaction = -q calorimeter. Details about coffee-cup calorimeter.
<h3>What is a calorimeter?</h3>
A calorimeter is an apparatus for measuring the heat generated or absorbed by either a chemical reaction, change of phase or some other physical change.
A coffee-cup calorimeter is a specific type of calorimeter that involves the absorption of heat of a reaction by water when a reaction occurs.
The enthalpy change of the reaction is equal in magnitude but opposite in sign to the heat flow for the water:
qreaction = -(qwater)
Therefore, the equation that is correct for coffee-cup calorimeter is q reaction = -q calorimeter.
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