Correct Question:
A chemist measures the enthalpy change ΔH during the following reaction: Fe(s) + 2HCl(g)-->FeCl2(s) + H2 ΔH=-157.0 kJ. Use this information to complete the table below. Round each of your answers to the nearest kJ/mol
Answer:
-314 kJ
+628 kJ
+157 kJ
Explanation:
The enthalpy change of a reaction measures the amount of heat that is lost or gained by it. If ΔH >0 the heat is gained, and the reaction is called endothermic, if ΔH<0, the heat is lost, and the reaction is called exothermic.
If the reaction is inverted, the value of ΔH is inverted too (the opposite endothermic reaction is exothermic), and if the reaction is multiplied by a constant, ΔH will be multiplied by it too.
1) 2Fe(s) + 4HCl --> 2FeCl2(s) + 2H2(g)
This reaction is the product of the given reaction by 2, so
ΔH = 2*(-157) = -314 kJ
2) 4FeCl2(s) + 4H2(g) --> 4Fe(s) + 8HCl(g)
This reaction is the inverted reaction given multiplied by 4, so
ΔH = 4*(157) = +628 kJ
3) FeCl2(s) + H2(g) --> Fe(s) + 2HCl
This reaction is the inverted reaction given, so
ΔH = +157 kJ
The overall reaction is given by:

The fast step reaction is given as:

The slow step reaction is given as:
(slow step
)
Now, the expression for the rate of reaction of fast reaction is:
![r_{1}=k_{1}[NO][Br_{2}]-k_{-1}[NOBr_{2}]](https://tex.z-dn.net/?f=r_%7B1%7D%3Dk_%7B1%7D%5BNO%5D%5BBr_%7B2%7D%5D-k_%7B-1%7D%5BNOBr_%7B2%7D%5D)
The expression for the rate of reaction of slow reaction is:
Slow step is the rate determining step. Thus, the overall rate of formation is the rate of formation of slow reaction as
takes place in this reaction.
The expression of rate of formation is:

=
(1)
Now, consider that the fast step is always is in equilibrium. Therefore, 
![k_{1}[NO][Br_{2}]= k_{-1}[NOBr_{2}]](https://tex.z-dn.net/?f=k_%7B1%7D%5BNO%5D%5BBr_%7B2%7D%5D%3D%20k_%7B-1%7D%5BNOBr_%7B2%7D%5D)
![[NOBr_{2}] = \frac{k_{1}}{k_{-1}}[NO][Br_{2}]](https://tex.z-dn.net/?f=%5BNOBr_%7B2%7D%5D%20%3D%20%5Cfrac%7Bk_%7B1%7D%7D%7Bk_%7B-1%7D%7D%5BNO%5D%5BBr_%7B2%7D%5D)
Substitute the value of
in equation (1), we get:
![\frac{d(NOBr)}{dt}=k_{2}[NOBr_{2}][NO]](https://tex.z-dn.net/?f=%5Cfrac%7Bd%28NOBr%29%7D%7Bdt%7D%3Dk_%7B2%7D%5BNOBr_%7B2%7D%5D%5BNO%5D)
=![k_{2} \frac{k_{1}}{k_{-1}}[NO][Br_{2}][NO]](https://tex.z-dn.net/?f=k_%7B2%7D%20%5Cfrac%7Bk_%7B1%7D%7D%7Bk_%7B-1%7D%7D%5BNO%5D%5BBr_%7B2%7D%5D%5BNO%5D)
= ![\frac{k_{1}k_{2}}{k_{-1}}[NO]^{2}[Br_{2}]](https://tex.z-dn.net/?f=%5Cfrac%7Bk_%7B1%7Dk_%7B2%7D%7D%7Bk_%7B-1%7D%7D%5BNO%5D%5E%7B2%7D%5BBr_%7B2%7D%5D)
Thus, rate law of formation of
in terms of reactants is given by
.
Answer: The molar mass and molecular weight of 4Fe is 223.38.
Answer:
Im not sure how to get it off but i know if you put like some make up or foundation it will cover it.
Explanation:
Are you being abused
Answer:
1.4 × 10^-4 M
Explanation:
The balanced redox reaction equation is shown below;
5Fe2+ + MnO4- + 8H+ --> 5Fe3+ +Mn2+ + 4H2O
Molar mass of FeSO4(NH4)2SO4*6H2O = 392 g/mol
Number of moles Fe^2+ in FeSO4(NH4)2SO4*6H2O = 3.47g/392g/mol = 8.85 × 10^-5 moles
Concentration of Fe^2+ = 8.85 × 10^-5 moles × 1000/200 = 4.425 × 10^-4 M
Let CA be concentration of Fe^2+ = 4.425 × 10^-4 M
Volume of Fe^2+ (VA)= 20.0 ml
Let the concentration of MnO4^- be CB (the unknown)
Volume of the MnO4^- (VB) = 12.6 ml
Let the number of moles of Fe^2+ be NA= 5 moles
Let the number of moles of MnO4^- be NB = 1 mole
From;
CAVA/CBVB = NA/NB
CAVANB = CBVBNA
CB= CAVANB/VBNA
CB= 4.425 × 10^-4 × 20 × 1/12.6 × 5
CB = 1.4 × 10^-4 M