PH of a solution will be <span>higher than 7
</span>
Ammonium cyanide is a salt formed by hydrogen cyanide and ammonia. Ammonia is a weak base and hydrogen cyanide is a weak acid.
NH₄CN + H₂O ⇒ NH₃ + HCN
NH₄⁺ + H₂O -----> H₃O⁺ + NH₃
CN⁻ + H₂O -----> HCN + OH⁻
Although both compounds are weak electrolytes, NH₃ is somewhat stronger base than HCN is a strong acid, so the solution reacts alkaline. We can prove this using Ka and Kb values:
Ka(HCN) = 4.9 x × 10⁻¹⁰
Kb(NH₃) = 1.8 × 10⁻⁵<span>
Kw= </span>1.0 × 10⁻¹⁴
Let's first calculate Ka for NH₄⁺:
Ka(NH₄⁺) x Kb(NH₃<span>) = pKw
</span>Ka(NH₄⁺) = Kw/Kb(NH₃) = 5.6 x 10⁻¹⁰
Then, Kb for CN⁻:
Kb(CN⁻) x Ka(HCN) = pKw
Kb(CN⁻) = Kw/Ka(HCN) = 2 x 10⁻⁵
From this, we can see that the acid constant NH4⁺ is much lower than the base constant of CN⁻, which will say that the solution of NH₄CN will react slightly alkaline because of the higher presence of hydroxyl ions in solution.
Answers and Explanation:
a)- The chemical equation for the corresponden equilibrium of Ka1 is:
2. HNO2(aq)⇌H+(aq)+NO−2
Because Ka1 correspond to a dissociation equilibrium. Nitrous acid (HNO₂) losses a proton (H⁺) and gives the monovalent anion NO₂⁻.
b)- The relation between Ka and the free energy change (ΔG) is given by the following equation:
ΔG= ΔGº + RT ln Q
Where T is the temperature (T= 25ºc= 298 K) and R is the gases constant (8.314 J/K.mol)
At the equilibrium: ΔG=0 and Q= Ka. So, we can calculate ΔGº by introducing the value of Ka:
⇒ 0 = ΔGº + RT ln Ka
ΔGº= - RT ln Ka
ΔGº= -8.314 J/K.mol x 298 K x ln (4.5 10⁻⁴)
ΔGº= 19092.8 J/mol
c)- According to the previous demonstation, at equilibrium ΔG= 0.
d)- In a non-equilibrium condition, we have Q which is calculated with the concentrations of products and reactions in a non equilibrium state:
ΔG= ΔGº + RT ln Q
Q= ((H⁺) (NO₂⁻))/(HNO₂)
Q= ( (5.9 10⁻² M) x (6.7 10⁻⁴ M) ) / (0.21 M)
Q= 1.88 10⁻⁴
We know that ΔGº= 19092.8 J/mol, so:
ΔG= ΔGº + RT ln Q
ΔG= 19092.8 J/mol + (8.314 J/K.mol x 298 K x ln (1.88 10⁻⁴)
ΔG= -2162.4 J/mol
Notice that ΔG<0, so the process is spontaneous in that direction.
Answer:
They all belong to the p block in the periodic table
Explanation:
Let us examine the electronic configuration of each element;
Oxygen - [He] 2s2 2p4
Silicon - [Ne] 3s2 3p2
Selenium - [Ar] 4s2 3d10 4p4
A common thread that joins all the elements listed above is that they all belong to the p-block in the periodic table. They could be collectively referred to as p-block elements.
Explanation:
Gravitational potential energy
= mgh
= (5kg)(9.81N/kg)(150m)
= 7357.5J.
