Answer:
The approximate molar enthalpy of combustion of this substance is -66 kJ/mole.
Explanation:
First we have to calculate the heat gained by the calorimeter.

where,
q = Heat gained = ?
c = Specific heat = 
ΔT = The change in temperature = 3.08°C
Now put all the given values in the above formula, we get:


Now we have to calculate molar enthalpy of combustion of this substance :

where,
= enthalpy change = ?
q = heat gained = 8.2544kJ
n = number of moles methane = 

Therefore, the approximate molar enthalpy of combustion of this substance is -66 kJ/mole.
From what i can gather it looks like d
Ionic bonds involve a cation and an anion. The bond is formed when an atom, typically a metal, loses an electron or electrons, and becomes a positive ion, or cation. Another atom, typically a non-metal, is able to acquire the electron(s) to become a negative ion, or anion.
One example of an ionic bond is the formation of sodium fluoride, NaF, from a sodium atom and a fluorine atom. In this reaction, the sodium atom loses its single valence electron to the fluorine atom, which has just enough space to accept it. The ions produced are oppositely charged and are attracted to one another due to electrostatic forces.
I think you add 29.57 + 80 and the answer would be 30.37