Instrumental methods of analysis rely on machines.The visualization of single molecules, single biological cells, biological tissues and nanomaterials is very important and attractive approach in analytical science.
There are several different types of instrumental analysis. Some are suitable for detecting and identifying elements, while others are better suited to compounds. In general, instrumental methods of analysis are:
-Fast
-Accurate (they reliably identify elements and compounds)
-Sensitive (they can detect very small amounts of a substance in a small amount of sample)
Answer:
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Explanation:
Este problema se puede resolver conociendo la relacion entre horas y minutos, sabemos que:
1 hora [h] → 60 minutos [min]
De esta manera:
2 [min] = 2/60 = 0.033 [h]
15 [min] = 15/60 = 0.25 [h]
30 [min] = 30/60 = 0.5 [h]
10 [min] = 10/60 = 0.166 [h]
6 [min] = 6/60 = 0.1 [h]
20 [min] = 20/60 = 0.33 [h]
5 [min] = 5/60 = 0.0833 [h]
Answer:
A. ΔG° = 132.5 kJ
B. ΔG° = 13.69 kJ
C. ΔG° = -58.59 kJ
Explanation:
Let's consider the following reaction.
CaCO₃(s) → CaO(s) + CO₂(g)
We can calculate the standard enthalpy of the reaction (ΔH°) using the following expression.
ΔH° = ∑np . ΔH°f(p) - ∑nr . ΔH°f(r)
where,
n: moles
ΔH°f: standard enthalpy of formation
ΔH° = 1 mol × ΔH°f(CaO(s)) + 1 mol × ΔH°f(CO₂(g)) - 1 mol × ΔH°f(CaCO₃(s))
ΔH° = 1 mol × (-635.1 kJ/mol) + 1 mol × (-393.5 kJ/mol) - 1 mol × (-1206.9 kJ/mol)
ΔH° = 178.3 kJ
We can calculate the standard entropy of the reaction (ΔS°) using the following expression.
ΔS° = ∑np . S°p - ∑nr . S°r
where,
S: standard entropy
ΔS° = 1 mol × S°(CaO(s)) + 1 mol × S°(CO₂(g)) - 1 mol × S°(CaCO₃(s))
ΔS° = 1 mol × (39.75 J/K.mol) + 1 mol × (213.74 J/K.mol) - 1 mol × (92.9 J/K.mol)
ΔS° = 160.6 J/K. = 0.1606 kJ/K.
We can calculate the standard Gibbs free energy of the reaction (ΔG°) using the following expression.
ΔG° = ΔH° - T.ΔS°
where,
T: absolute temperature
<h3>A. 285 K</h3>
ΔG° = ΔH° - T.ΔS°
ΔG° = 178.3 kJ - 285K × 0.1606 kJ/K = 132.5 kJ
<h3>B. 1025 K</h3>
ΔG° = ΔH° - T.ΔS°
ΔG° = 178.3 kJ - 1025K × 0.1606 kJ/K = 13.69 kJ
<h3>C. 1475 K</h3>
ΔG° = ΔH° - T.ΔS°
ΔG° = 178.3 kJ - 1475K × 0.1606 kJ/K = -58.59 kJ
In chemical reactions, the actual yield is not the same as the expected yield . Actual yield is lower than the theoretical yield . Then we have to find the yield percentage. To see what percentage of the theoretical yield is the actual yield.
Percent yield = actual yield / theoretical yield x 100%
Percent yield = 24.6/55.9 x100%
Percent yield = 44%
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