The first one because some people might not believe that and others might believe that.
Answer:
d. 8 moles of H2O on the product side
Explanation:
Hello,
In this case, we need to balance the given redox reaction in acidic media as shown below:
![MnO_4^{1-} (aq) + Cl^{1-} (aq) \rightarrow Mn^{2+} (aq) + Cl_2 (g)\\\\(Mn^{7+}O^{2-}_4)^{1-} (aq) + Cl^{1-} (aq) \rightarrow Mn^{2+} (aq) + Cl_2 (g)\\\\\\\\(Mn^{7+}O^{2-}_4)^{1-} (aq)+8H^++5e^- \rightarrow Mn^{2+}+4H_2O\\\\2Cl^{1-}\rightarrow Cl_2^0+2e^-\\\\2*[(Mn^{7+}O^{2-}_4)^{1-} (aq)+8H^++5e^- \rightarrow Mn^{2+}+4H_2O]\\\\5*[2Cl^{1-}\rightarrow Cl_2^0+2e^-]\\\\\\\\2(Mn^{7+}O^{2-}_4)^{1-} (aq)+16H^++10e^- \rightarrow 2Mn^{2+}+8H_2O\\\\10Cl^{1-}\rightarrow 5Cl_2^0+10e^-\\](https://tex.z-dn.net/?f=MnO_4%5E%7B1-%7D%20%28aq%29%20%2B%20Cl%5E%7B1-%7D%20%28aq%29%20%5Crightarrow%20%20Mn%5E%7B2%2B%7D%20%28aq%29%20%2B%20Cl_2%20%28g%29%5C%5C%5C%5C%28Mn%5E%7B7%2B%7DO%5E%7B2-%7D_4%29%5E%7B1-%7D%20%28aq%29%20%2B%20Cl%5E%7B1-%7D%20%28aq%29%20%5Crightarrow%20%20Mn%5E%7B2%2B%7D%20%28aq%29%20%2B%20Cl_2%20%28g%29%5C%5C%5C%5C%5C%5C%5C%5C%28Mn%5E%7B7%2B%7DO%5E%7B2-%7D_4%29%5E%7B1-%7D%20%28aq%29%2B8H%5E%2B%2B5e%5E-%20%5Crightarrow%20Mn%5E%7B2%2B%7D%2B4H_2O%5C%5C%5C%5C2Cl%5E%7B1-%7D%5Crightarrow%20Cl_2%5E0%2B2e%5E-%5C%5C%5C%5C2%2A%5B%28Mn%5E%7B7%2B%7DO%5E%7B2-%7D_4%29%5E%7B1-%7D%20%28aq%29%2B8H%5E%2B%2B5e%5E-%20%5Crightarrow%20Mn%5E%7B2%2B%7D%2B4H_2O%5D%5C%5C%5C%5C5%2A%5B2Cl%5E%7B1-%7D%5Crightarrow%20Cl_2%5E0%2B2e%5E-%5D%5C%5C%5C%5C%5C%5C%5C%5C2%28Mn%5E%7B7%2B%7DO%5E%7B2-%7D_4%29%5E%7B1-%7D%20%28aq%29%2B16H%5E%2B%2B10e%5E-%20%5Crightarrow%202Mn%5E%7B2%2B%7D%2B8H_2O%5C%5C%5C%5C10Cl%5E%7B1-%7D%5Crightarrow%205Cl_2%5E0%2B10e%5E-%5C%5C)
Then, we add the half reactions:
Thereby, we can see d. 8 moles of H2O on the product side.
Best regards.
Answer:
the heat of formation of isopropyl alcohol is -317.82 kJ/mol
Explanation:
The heat of combustion of isopropyl alcohol is given as follows;
C₃H₇OH (l) +(9/2)O₂ → 3CO₂(g) + 4H₂O (g)
The heat of combustion of CO₂ and H₂O are given as follows
C (s) + O₂ (g) → CO₂(g) = −393.50 kJ
H₂ (g) + 1/2·O₂(g) → H₂O (l) = −285.83 kJ
Therefore we have
3CO₂(g) + 4H₂O (g) → C₃H₇OH (l) +(9/2)O₂ which we can write as
3C (s) + 3O₂ (g) → 3CO₂(g) = −393.50 kJ × 3 =
4H₂ (g) + 2·O₂(g) → 4H₂O (l) = −285.83 kJ × 4
3CO₂(g) + 4H₂O (g) → C₃H₇OH (l) +(9/2)O₂ = +2006 kJ/mol
-1180.5 - 1143.32 +2006 = -317.82 kJ/mol
Therefore, the heat of formation of isopropyl alcohol = -317.82 kJ/mol.
Half reaction 1: 2Fe° → Fe₂³⁺ + 6e⁻ /×2.
4Fe° → 2Fe₂³⁺ + 12e⁻.
Iron is oxidized from neutral charge (0) to oxidation number +3, one iron lose three electrons, two irons lose six electrons and four irons twelve electrons.
Half reaction 2: 12e⁻ + 3O₂ → 2O₃²⁻
Oxygen is reduced from neutral chage to oxidation number -2, one oxygen gain two electrons, six oxygens gain twelve electrons.
Balanced chemical reaction: 4Fe + 3O₂ → 2Fe₂O₃.
