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AveGali [126]
3 years ago
8

A solution of NaF is added dropwise to a solution that is 0.0144 M in Ba 2 . When the concentration of F - exceeds __________ M,

BaF 2 will precipitate. Neglect volume changes. For BaF 2,
Chemistry
1 answer:
Stella [2.4K]3 years ago
5 0

Answer:

When [F⁻] exceeds 0.0109M concentration, BaF₂ will precipitate

Explanation:

Ksp of BaF₂ is:

BaF₂(s) ⇄ Ba²⁺(aq) + 2F⁻(aq)

Ksp = 1.7x10⁻⁶ = [Ba²⁺] [F⁻]²

The solution will produce BaF₂(s) -precipitate- just when [Ba²⁺] [F⁻]² > 1.7x10⁻⁶.

As the concentration of [Ba²⁺] is 0.0144M, the product [Ba²⁺] [F⁻]² will be equal to  ksp just when:

1.7x10⁻⁶ = [Ba²⁺] [F⁻]²

1.7x10⁻⁶ = [0.0144M] [F⁻]²

1.18x10⁻⁴ = [F⁻]²

0.0109M = [F⁻]

That means, when [F⁻] exceeds 0.0109M concentration, BaF₂ will precipitate

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In the reaction BaCO3 + 2HNO3 + Ba(NO3)2 + CO2 + H2O, what mass of Ba(NO3)2 can be formed by combining 55 g BaCO3 and 26 g HNO3
Nataliya [291]

From the stoichiometry of the reaction, the mass of barium nitrate produced is 54.9 g.

<h3>Stoichiometry</h3>

The term stoichiometry refers to mass - volume relationships. Stoichiometry can be used to calculate the amount, mass or volume of reactants and products from the balanced reaction equation.

The equation of the reaction is written as follows;

BaCO3 + 2HNO3 ------>  Ba(NO3)2 + CO2 + H2O

Number of moles of BaCO3  = 55 g/197.34 g/mol = 0.28 moles

Number of moles of HNO3 = 26 g/63.01 g/mol = 0.41 moles

From the reaction equation;

1 mole of BaCO3 reacts with 2 moles of HNO3

0.28 moles of BaCO3 reacts with 0.28 moles ×  2 moles/1 mole = 0.56 moles

There is not enough HNO3 hence it is the limiting reactant.

Number of moles of Ba(NO3)2 produced  is obtained from;

2 moles of HNO3  yields 1 mole of Ba(NO3)2

0.41 moles of HNO3  yields 0.41 moles × 1 mole/2 moles

= 0.21 moles of Ba(NO3)2

Mass of  Ba(NO3)2  = 0.21 moles  × 261.337 g/mol = 54.9 g

Learn more about stoichiometry: brainly.com/question/9743981

8 0
3 years ago
What volume of 0.500 m h2so4 is needed to react completely with 20.0 ml of 0.400 m lioh?
ExtremeBDS [4]
The balanced chemical equation for the above reaction is as follows;
2LiOH + H₂SO₄ ---> Li₂SO₄ + 2H₂O
stoichiometry of base to acid is 2:1
Number of OH⁻ moles reacted = number of H⁺ moles reacted at neutralisation
Number of LiOH moles reacted = 0.400 M / 1000 mL/L x 20.0 mL = 0.008 mol 
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Number of H₂SO₄ moles in 1 L - 0.500 M
This means that 0.500 mol  in 1 L solution 
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3 years ago
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mars1129 [50]
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6 0
3 years ago
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MY NOTES ASK YOUR TEACHER Consider a different titrant for this exercise. Suppose Ca(OH)2 were used as the titrant, instead of N
Alekssandra [29.7K]

Answer:

Two moles of HC2H3O2 react with one mole of Ca(OH)2 to produce one mole of calcium acetate and two moles of water.

Explanation:

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when Ca(OH)2 reacts with Acetic acid the product formed will be Calcium acetate and water

Chemically the reaction can be represented as

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Two moles of CH3COOH react with one mole of Ca(OH)2 to produce one mole of Ca(CH3COO)2 and two moles of H2O.

7 0
3 years ago
List and explain the four most important factors that control the relative reactivity of a carbonyl-containing functional group
ioda

Resonance, leaving group, carbonyl carbon delta+, and steric effect is the most crucial variables that affect the relative reactivity of a functional group containing a carbonyl in an addition or substitution process.

Discussion:

1. Carbonyl Carbon Delta+: The carbonyl group becomes more electrophilic and accelerates nucleophilic assault when the carbonyl carbon delta+ is bigger.

2. Resonance: When the carbonyl is transformed into the tetrahedral adduct, it may be lost. Loss of resonance increases the energy of the transition state for this nucleophilic assault because resonance has the function of stabilizing. Therefore, a carbonyl functional group's resistance to nucleophilic attack increases as resonance in the group increases in importance.

3. Leaving group: Tetrahedral adduct fragmentation is encouraged by a better LG.

4. Steric effects: The nucleophilic attack on carbonyl carbon is delayed when sterically impeded.

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1 year ago
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