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irina [24]
3 years ago
7

g A gas is compressed in a cylinder from a volume of 20.0 L to 2.0 L by a constant pressure of 10.0 atm. Calculate the amount of

work done on the system in Joules. (1 L.atm
Chemistry
1 answer:
Lemur [1.5K]3 years ago
5 0

Answer:

The amount of work done on the system is 18234 J and the final positive sign means that this work corresponds to an increase in internal energy of the gas.

Explanation:

Thermodynamic work is called the transfer of energy between the system and the environment by methods that do not depend on the difference in temperatures between the two. When a system is compressed or expanded, a thermodynamic work is produced which is called pressure-volume work (p - v).

The pressure-volume work done by a system that compresses or expands at constant pressure is given by the expression:

W system= -p*∆V

Where:

  • W system: Work exchanged by the system with the environment. Its unit of measure in the International System is the joule (J)
  • p: Pressure. Its unit of measurement in the International System is the pascal (Pa)
  • ∆V: Volume variation (∆V = Vf - Vi). Its unit of measurement in the International System is cubic meter (m³)

In this case:

  • p= 10 atm= 1.013*10⁶ Pa (being 1 atm= 101325 Pa)
  • ΔV= 2 L- 20 L= -18 L= -0.018 m³ (being 1 L=0.001 m³)

Replacing:

W system= -1.013*10⁶ Pa* (-0.018 m³)

Solving:

W system= 18234 J

<u><em>The amount of work done on the system is 18234 J and the final positive sign means that this work corresponds to an increase in internal energy of the gas.</em></u>

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State the oxidation number of S in <br><img src="https://tex.z-dn.net/?f=H_%7B2%7DSO_%7B3%7D" id="TexFormula1" title="H_{2}SO_{3
Nezavi [6.7K]

Taking into account the definition of oxidation number, the oxidation numbers of S in H₂SO₃ is 4.

<h3>Definition of oxidation number</h3>

The oxidation number is the charge that an atom has; is an integer that represents the number of electrons an atom puts into play when it forms a given compound.

In other words, the oxidation number of an element is a value that indicates the number of electrons that element gains or loses when it combines with another.

<h3>Oxidation number determination</h3>

To determine the oxidation state of different elements it is necessary to know that:

  • The oxidation number of hydrogen in a compound is +1, except in metal hydrides, where is –1.
  • The oxidation number of oxygen in a compound is –2, except in peroxides, where it is –1.

On the other side, the sum of the oxidation numbers of the existing elements in a chemical formula must add up to zero.

Then, considering the oxidation numbers of each element, multiplying it by the number of existing elements in the chemical formula and adding it and equaling it to zero, the value of the missing oxidation number can be obtained.

<h3>Oxidation numbers of S</h3>

In this case, the oxidation numbers of S in H₂SO₃ is calculated as:

2× (+1) + oxidation numbers of S + 3×(-2)= 0

2 + oxidation numbers of S -6= 0

oxidation numbers of S -4= 0

<u><em>oxidation numbers of S= 4</em></u>

Finally, the oxidation numbers of S in H₂SO₃ is 4.

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5 0
2 years ago
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What property of a wave is measuered by f
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Frequency is represented by f in the formula v=fπ. Where π is wavelength , f is frequency and v is velocity. Frequency is the number of waves passing per unit time.
6 0
3 years ago
Write a balanced equation from each cell notation:(b) Fe(s) | Fe²⁺(aq) | NO₃⁻(aq) | NO(g) | Pt(s)
tatiyna

The balanced redox reaction is

3Fe + 2NO₃⁻+ 8H+ → 3Fe²⁺ + 2NO + 4H2O

<h3>What is Galvanic cell? </h3>

It is a device that is used for the conversion of the chemical energy which is produce in the redox reaction into the electrical energy. It is also termed as the voltaic cell or electrochemical cell.

In the voltaic cell, at anode which is negative electrode of voltaic cell oxidation occurs and at the cathode which is positive electrode, reduction occurs

<h3>What is redox reaction? </h3>

The reaction in which both reduction and oxidation reaction takes place simultaneously is known as redox reaction.

<h3>What is oxidation reaction? </h3>

The reaction in which a substance or compound or species looses its electrons. In this reaction, oxidation state of an element increases.

<h3>What is reduction reaction? </h3>

The reaction in which a substance or compound or species accept the electrons. In this reaction, oxidation state of an element decreases.

The given two-half reactions are:

At anode:

3Fe → 3Fe²⁺ + 6e-

At cathode:

8H(+) + 2NO₃⁻ → 2NO + 4H2O

Redox reaction:

3Fe + 2NO₃⁻+ 8H+ → 3Fe²⁺ + 2NO + 4H2O

According to the voltaic cell, the half-cell reaction (1) shows oxidation reaction therefore, it occurs at anode and the half-cell reaction (2) shows reduction reaction therefore, it occurs at cathode.

Thus, we concluded that the redox reaction is

3Fe + 2NO₃⁻+ 8H+ → 3Fe²⁺ + 2NO + 4H2O

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7 0
2 years ago
If 21.00 mL of a 0.68 M solution of C6H5NH2 required 6.60 mL of the strong acid to completely neutralize the solution, what was
Andru [333]

Answer:

pH = 2.46

Explanation:

Hello there!

In this case, since this neutralization reaction may be assumed to occur in a 1:1 mole ratio between the base and the strong acid, it is possible to write the following moles and volume-concentrations relationship for the equivalence point:

n_{acid}=n_{base}=n_{salt}

Whereas the moles of the salt are computed as shown below:

n_{salt}=0.021L*0.68mol/L=0.01428mol

So we can divide those moles by the total volume (0.021L+0.0066L=0.0276L) to obtain the concentration of the final salt:

[salt]=0.01428mol/0.0276L=0.517M

Now, we need to keep in mind that this is an acidic salt since the base is weak and the acid strong, so the determinant ionization is:

C_6H_5NH_3^++H_2O\rightleftharpoons  C_6H_5NH_2+H_3O^+

Whose equilibrium expression is:

Ka=\frac{[C_6H_5NH_2][H_3O^+]}{C_6H_5NH_3^+}

Now, since the Kb of C6H5NH2 is 4.3 x 10^-10, its Ka is 2.326x10^-5 (Kw/Kb), we can also write:

2.326x10^{-5}=\frac{x^2}{0.517M}

Whereas x is:

x=\sqrt{0.517*2.326x10^{-5}}\\\\x=3.47x10^-3

Which also equals the concentration of hydrogen ions; therefore, the pH at the equivalence point is:

pH=-log(3.47x10^{-3})\\\\pH=2.46

Regards!

6 0
3 years ago
Methane gas reacts with oxygen in a gas stove.
nekit [7.7K]

Hey there!

CH₄ + 2O₂ → CO₂ + 2H₂O

carbon dioxide: product

methane: reactant

oxygen: reactant

water: product

Methane and oxygen are reactants because they are the substances we start with. They are on the side of the equation that the arrow is pointing away from.

Carbon dioxide and water are products because they are the new substances  that are the yields of the equation. They are on the side of the equation that the arrow is pointing towards.

Hope this helps!

7 0
3 years ago
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