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irina [24]
2 years ago
7

g A gas is compressed in a cylinder from a volume of 20.0 L to 2.0 L by a constant pressure of 10.0 atm. Calculate the amount of

work done on the system in Joules. (1 L.atm
Chemistry
1 answer:
Lemur [1.5K]2 years ago
5 0

Answer:

The amount of work done on the system is 18234 J and the final positive sign means that this work corresponds to an increase in internal energy of the gas.

Explanation:

Thermodynamic work is called the transfer of energy between the system and the environment by methods that do not depend on the difference in temperatures between the two. When a system is compressed or expanded, a thermodynamic work is produced which is called pressure-volume work (p - v).

The pressure-volume work done by a system that compresses or expands at constant pressure is given by the expression:

W system= -p*∆V

Where:

  • W system: Work exchanged by the system with the environment. Its unit of measure in the International System is the joule (J)
  • p: Pressure. Its unit of measurement in the International System is the pascal (Pa)
  • ∆V: Volume variation (∆V = Vf - Vi). Its unit of measurement in the International System is cubic meter (m³)

In this case:

  • p= 10 atm= 1.013*10⁶ Pa (being 1 atm= 101325 Pa)
  • ΔV= 2 L- 20 L= -18 L= -0.018 m³ (being 1 L=0.001 m³)

Replacing:

W system= -1.013*10⁶ Pa* (-0.018 m³)

Solving:

W system= 18234 J

<u><em>The amount of work done on the system is 18234 J and the final positive sign means that this work corresponds to an increase in internal energy of the gas.</em></u>

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This is an exercise in<u> the General Combined Gas Law</u>.

To start solving this exercise, we obtain the following data:

<h3>Data:</h3>
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\large\displaystyle\text{$\begin{gathered}\sf P_{2}=\frac{P_{1}V_{1}T_{2}}{V_{2}T_{1}} \ \ \to \ \ \ Formula \end{gathered}$}

We substitute our data into the formula:

\large\displaystyle\text{$\begin{gathered}\sf P_{2}=\frac{(365 \ mmHg)(4.00 \not{l})(303 \not{K})}{(2.80 \not{l})(293\not{K})}  \end{gathered}$}

\large\displaystyle\text{$\begin{gathered}\sf P_{2}=\frac{442380 \ mmHg}{ 820.4 }  \end{gathered}$}

\boxed{\large\displaystyle\text{$\begin{gathered}\sf P_{2}=539.224 \ mmHg \end{gathered}$}}

Answer: The new canister pressure is 539.224 mmHg.

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