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mezya [45]
3 years ago
10

The reaction A→B is to be carried out isothermally in a continuous-flow reactor. Calculate the PFR volume to consume 99% of A (C

A = 0.01CA0) when the entering molar flow rate is 5 mol/h (assume pure A), the volumetric flow rate is constant at 10 dm3 /h and the rate is: -rA=3CA 2 [ dm3 /mol•h]
Chemistry
1 answer:
RoseWind [281]3 years ago
5 0

Answer:

Explanation:

From the information above:

The equation for the reactor volume of CSTR is given by the formula:

V = \dfrac{C_{Ao}V_o - C_A V_o }{-rA}

V = \dfrac{C_{Ao}V_o (1 - 0.01)}{KC_A^2}

The reaction rate of A is:

-r_A = kC_A^2 and k = 3 dm³/mol.h

replacing the values in the above equation to solve for v;

∴

V = \dfrac{(0.5 \ mol/dm^3) (10 \ dm^3/h)  (1 - 0.01)}{ ( 3 \ dm^3/mol.h) (0.01 \times 0.5 \ mol/dm^3)^2}

V = 66,000 dm³

Thus, the reactor volume of CSTR is 66000 dm³

Taking the differential mole balance equation for PFR is as follows:

\dfrac{d(C_AV_o)}{dV} = -r_A

\dfrac{d(C_AV_o)}{dV} = Kc^2A

Taking the integral between initial and final concentrations;

\dfrac{v_o}{k} \int ^{C_A}_{C_{Ao}} \dfrac{dC_A}{C^2A}= - \int ^V_o \ dV

V = \dfrac{V_o}{K} \Big [\dfrac{1}{C_A}- \dfrac{1}{C_{Ao}} \Big ]

replace the values in the above equation;

V= \dfrac{(10 \ dm^3/h) }{(3 \ dm^3/mol.h)}\Big [ \dfrac{1}{0.01(0.5 \ mol/dm^3)} - \dfrac{1}{0.5 \ mol/dm^3}   \Big ]

\mathbf{V = 66 0 \ dm^3}

Thus, the reactor volume of PFR is 660 dm³

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