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AleksAgata [21]
3 years ago
12

I was checking my answers for a chem test and came across a solution for a problem where the ∆S was pos, ∆H was neg and ∆G was n

eg. I believed it was only favorable at low temps, as reactions with a negative ∆H and negative ∆S are spontaneous at low temperatures. I was incorrect and the reaction was favorable at higher temps like 90 C as well.
Is a reaction always favorable if the ∆G is negative (at all temps)? What about when the ∆S is positive? If it's not favorable in all situations, what temps would cause it to be favorable? What role does ∆H play in determining the favorability of a reaction?

PLS HELP I WILL GIVE 30 POINTS AND NAME BRAINLIEST
Chemistry
1 answer:
nevsk [136]3 years ago
8 0

Answer:

there is only 15 points

Explanation:

The second law of thermodynamics says that the entropy of the universe always increases for a spontaneous process: \Delta \text {S}_{\text{universe}}=\Delta \text {S}_{\text{system}} + \Delta \text {S}_{\text{surroundings}} > 0ΔS  

universe

​

=ΔS  

system

​

+ΔS  

surroundings

​

>0delta, start text, S, end text, start subscript, start text, u, n, i, v, e, r, s, e, end text, end subscript, equals, delta, start text, S, end text, start subscript, start text, s, y, s, t, e, m, end text, end subscript, plus, delta, start text, S, end text, start subscript, start text, s, u, r, r, o, u, n, d, i, n, g, s, end text, end subscript, is greater than, 0

At constant temperature and pressure, the change in Gibbs free energy is defined as \Delta \text G = \Delta \text H - \text{T}\Delta \text SΔG=ΔH−TΔSdelta, start text, G, end text, equals, delta, start text, H, end text, minus, start text, T, end text, delta, start text, S, end text.

When \Delta \text GΔGdelta, start text, G, end text is negative, a process will proceed spontaneously and is referred to as exergonic.

The spontaneity of a process can depend on the temperature.

Spontaneous processes

In chemistry, a spontaneous processes is one that occurs without the addition of external energy. A spontaneous process may take place quickly or slowly, because spontaneity is not related to kinetics or reaction rate. A classic example is the process of carbon in the form of a diamond turning into graphite, which can be written as the following reaction:

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Explanation:

Let's consider the reduction of Zn(II) that occurs in an electrolysis bath.

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We can establish the following relations:

  • 1 min = 60 s
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The mass of Zn deposited under these conditions is:

24min \times \frac{60s}{1min} \times \frac{6.5C}{s} \times \frac{1mol\ e^{-} }{96,468C} \times \frac{1molZn}{2mol\ e^{-}}  \times \frac{65.38g}{1molZn} = 3.17 g

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What is the concentration of NaCl in a solution if titration of 15.00 mL of the solution with 0.2503 M AgNO3 requires 20.22 mL o
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Answer:

The concentration of NaCl = 0.3374 M

Explanation:

Given :

Molarity of AgNO₃ = 0.2503 M

Volume of AgNO₃ = 20.22 mL

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1 mL= 10^{-3} L

Thus, volume of the solution = 20.22×10⁻³ L

Molarity of a solution is the number of moles of solute present in 1 L of the solution.

Molarity=\frac{Moles\ of\ solute}{Volume\ of\ the\ solution}

The formula can be written for the calculation of moles as:

Molarity=\frac{Moles\ of\ solute}{Volume\ of\ the\ solution}

Thus,  

Moles\ of\ AgNO_3 =Molarity \times {Volume\ of\ the\ solution}

Moles\ of\ AgNO_3 =0.2503 \times {20.22\times 10^{-3}}\ moles

Moles\ of\ AgNO_3 = 5.0611 \times 10^{-3} moles

The chemical reaction taking place:

AgNO_3_(aq) + NaCl_(aq) \rightarrow AgCl_(s) + NaNO_3_(aq)

According to reaction stoichiometry:

<u>1 mole</u> of AgNO₃ reacts with <u>1 mole</u> of NaCl

Thus,

5.0611×10⁻³ moles of AgNO₃ reacts with 5.0611×10⁻³ moles of NaCl

Thus, moles of NaCl required = 5.0611×10⁻³ moles

Volume of NaCl required = 15.00 mL

The conversion of mL into L is shown below:

1 mL= 10^{-3} L

Thus, volume of the solution = 15.00×10⁻³ L

Applying in the formula of molarity as:

Molarity=\frac{Moles\ of\ solute}{Volume\ of\ the\ solution}

Molarity\ of\ NaCl=\frac{5.0611\times 10^{-3}}{15.00\times 10^{-3}}

Molarity\ of\ NaCl= 0.3374 M

<u>Thus, the concentration of NaCl = 0.3374 M</u>

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I want to know the steps.
Artyom0805 [142]

The answer for the following problem is described below.

<em><u> Therefore the standard enthalpy of combustion is -2800 kJ</u></em>

Explanation:

Given:

enthalpy of combustion of glucose(ΔH_{f} of C_{6}H_{12} O_{6}) =-1275.0

enthalpy of combustion of oxygen(ΔH_{f} of O_{2}) = zero

enthalpy of combustion of carbon dioxide(ΔH_{f} of CO_{2}) = -393.5

enthalpy of combustion of water(ΔH_{f} of H_{2} O) = -285.8

To solve :

standard enthalpy of combustion

We know;

ΔH_{f}  = ∈ΔH_{f} (products) - ∈ΔH_{f} (reactants)

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ΔH_{f} = [6 (-393.5) + 6(-285.8)] - [6 (0) + (-1275)]

ΔH_{f} = [6 (-393.5) + 6(-285.8)] - [0 - 1275]

ΔH_{f} = 6 (-393.5) + 6(-285.8)  - 0 + 1275

ΔH_{f} = -2361 - 1714 - 0 + 1275

ΔH_{f} =-2800 kJ

<em><u> Therefore the standard enthalpy of combustion is -2800 kJ</u></em>

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