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bearhunter [10]
3 years ago
10

assume in a different experiment, you prepare a mixture containing 10.0 M FeSCN2+, 1.0 M H+, 0.1 MFe3+ and 0.1 M HSCN. Is the in

itial mixture at equilibrium? If not, in what direction must the reactionproceed to reach equilibrium? (Hint: You will need to use the value of Kc you determined in the lab
Chemistry
1 answer:
Katarina [22]3 years ago
7 0

Answer:

The mixture is not in equilibrium, the reaction will shift to the left.

Explanation:

<em>Based on the equilibrium:</em>

<em>Fe³⁺+ HSCN ⇄ FeSCN²⁺ + H⁺</em>

<em>kc = 30 = [FeSCN²⁺] [H⁺] / [Fe³⁺] [HSCN]</em>

Where [] are concentrations at equilibrium. The reaction is in equilibrium when  the ratio of concentrations = kc

Q is the same expression than kc but with [] that are not in equilibrium

Replacing:

Q = [10.0M] [1.0M] / [0.1M] [0.1M]

Q = 1000

As Q > kc, the reaction will shift to the left in order to produce Fe³⁺ and HSCN untill Q = Kc

<em> </em>

<em> </em>

<em />

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By what factor would a scuba diver’s lungs expand if she ascended rapidly to the surface from a depth of 125 ft without inhaling
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It is found that scuba diver’s can safely ascend up to 52.53 ft without Breathing out.

By what factor would a scuba diver’s lungs expand if she ascended rapidly to the surface from a depth of 125 ft without inhaling or exhaling then

p_{1} =patm+pH_{2} O

p_{1} = 101325+ρgh_{1}

It is given that height is 125ft. Put the value of h in above formula:

h1  =125ft=38.1m

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p_{1}   =490036.44‬Pa                

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It is known that volume and pressure can be expressed as:

V*P=const.

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V_{1} *p_{1} =V_{2}  *p_{2}

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Assume constant temperature

d of seawater = 1.04 g/mL; d of Hg = 13.5 g/mL.

now p_{1} =p atm​+pH_{2} O =490036.44Pa

V*p=const                              

where, V is volume and P is pressure.

Now,              

V_{1} *p_{1} =V_{2}  *p_{2}

V_{2} /V_{1}=p_{2} /p_{1}

V_{2} /V_{1} =490036.44/X

p_{2} =490036.44pa/(V2/V1) =326690.96Pa

p_{2} =patm +pH_{2} O

p_{2} =101325Pa+ρgh_{2}

326690.96Pa=101325Pa+ρgh_{2}

ρgh1  =151987.5-101325=225365.96‬‬Pa

ρ=1,04g/mL=1040kg/m3

g=9.81

h_{2} =225365.96/‬ρ∗g

​h_{2}  =225365.96  / ‬1040∗9.81

h_{2}  =22.09m= 72.47ft

ΔH=H_{1} -H_{2}

=125-72.47

=52.53ft

So she can safely ascend up to 52.53 ft without Breathing out

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