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Elina [12.6K]
3 years ago
7

During convention _______, less dense fluid rises and _______, denser fluid sinks

Chemistry
1 answer:
ivann1987 [24]3 years ago
5 0

Answer:

Dad

Explanation:

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You have two cups one is 6cm and other 10cm with no measurement and you have to pour 8cm of water into the 10cm cup using the tw
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Here’s one way to do it.

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Your friend Niko predicts that iron and silver nitrate will form when silver is placed into an iron (III) nitrate solution. Is t
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After the solution reaches equilibrium, what concentration of Ni2+(aq) remains? The value of Kf for Ni(NH3)62+ is 2.0×108. Expre
Marina CMI [18]

Answer:

\large \boxed{1.77 \times 10^{-5}\text{ mol/L}}

Explanation:

Assume that you have mixed 135 mL of 0.0147 mol·L⁻¹ NiCl₂ with 190 mL of 0.250 mol·L⁻¹ NH₃.

1. Moles of Ni²⁺

n = \text{135 mL} \times \dfrac{\text{0.0147 mmol}}{\text{1 mL}} = \text{1.984 mmol}

2. Moles of NH₃

n = \text{190 mL} \times \dfrac{\text{0.250 mmol}}{\text{1 mL}} = \text{47.50 mmol}

3. Initial concentrations after mixing

(a) Total volume

V = 135 mL + 190 mL = 325 mL

(b) [Ni²⁺]

c = \dfrac{\text{1.984 mmol}}{\text{325 mL}} = 6.106 \times 10^{-3}\text{ mol/L}

(c) [NH₃]

c = \dfrac{\text{47.50 mmol}}{\text{325 mL}} = \text{0.1462 mol/L}

3. Equilibrium concentration of Ni²⁺

The reaction will reach the same equilibrium whether it approaches from the right or left.

Assume the reaction goes to completion.

                        Ni²⁺             +             6NH₃       ⇌       Ni(NH₃)₆²⁺

I/mol·L⁻¹:    6.106×10⁻³                     0.1462                       0

C/mol·L⁻¹:  -6.106×10⁻³         0.1462-6×6.106×10⁻³             0

E/mol·L⁻¹:           0                              0.1095                6.106×10⁻³

Then we approach equilibrium from the right.

                            Ni²⁺   +   6NH₃       ⇌       Ni(NH₃)₆²⁺

I/mol·L⁻¹:              0           0.1095                6.106×10⁻³

C/mol·L⁻¹:            +x            +6x                           -x

E/mol·L⁻¹:             x         0.1095+6x            6.106×10⁻³-x

K_{\text{f}} = \dfrac{\text{[Ni(NH$_{3}$)$_{6}^{2+}$]}}{\text{[Ni$^{2+}$]}\text{[NH$_{3}$]}^{6}} = 2.0 \times 10^{8}

Kf is large, so x ≪ 6.106×10⁻³. Then

K_{\text{f}} = \dfrac{\text{[Ni(NH$_{3}$)$_{6}^{2+}$]}}{\text{[Ni$^{2+}$]}\text{[NH$_{3}$]}^{6}} = 2.0 \times 10^{8}\\\\\dfrac{6.106 \times 10^{-3}}{x\times 0.1095^{6}} = 2.0 \times 10^{8}\\\\6.106 \times 10^{-3} = 2.0 \times 10^{8}\times 0.1095^{6}x= 345.1x\\x= \dfrac{6.106 \times 10^{-3}}{345.1} = 1.77 \times 10^{-5}\\\\\text{The concentration of Ni$^{2+}$ at equilibrium is $\large \boxed{\mathbf{1.77 \times 10^{-5}}\textbf{ mol/L}}$}

 

3 0
3 years ago
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