There can be a lot of meanings for isomers. In this case, we are showing the structural isomers of C₇H₁₆. Based on the chemical formula, CₓH₂ₓ₊₂ it is an alkane. They only differ in the positions of methane branches in the parent carbon chain. Basing on the attached picture, the parent carbon chain is pentane for both isomers. But the methyl branches are on the 2nd & 4th, and 2nd & 3rd carbon for 2,4 - dimethylpentane and 2,3 - dimethylpentane, respectively.
<h3><u>Full Question:</u></h3>
The following compound has been found effective in treating pain and inflammation (J. Med. Chem. 2007, 4222). Which sequence correctly ranks each carbonyl group in order of increasing reactivity toward nucleophilic addition?
A) 1 < 2 < 3
B) 2 < 3 < 1
C) 3 < 1 < 2
D) 1 < 3 < 2
<h3><u>Answer: </u></h3>
The rate of nucleophilic attack of carbonyl compounds is 2<3 <1.
Option B
<h3><u>Explanation. </u></h3>
Nucleophilic attack is explained as the attack of an electron rich radical to a carbonyl compound like aldehyde or a ketone. A nucleophile has a high electron density, so it searches for a electropositive atom where it can donate a portion of its electron density and become stable.
A carbonyl compound is a
hybridized carbon atom with a double bonded oxygen atom in it. The oxygen atom pulls a huge portion of electron density from carbon being very electropositive.
In a ketone, there are two factors that make it less likely to undergo a nucleophilic attack than aldehyde. Firstly, the steric hindrance of two carbon groups being attached with the carbonyl carbon makes it harder for the nucleophile to approach. Secondly, the electron push by the carbon groups attached makes the carbonyl carbon a bit less electropositive than the aldehyde one. So aldehydes are more reactive towards a nucleophilic addition reaction.
Well, yeah, because the chemicals in the AlkaSeltzer when in water, fizes, because of the chemicals in the pallet.
B. 3.0 mol·L⁻¹ NaCl
Explanation:
Freezing point is a colligative property: it depends only on the number of particles in solution.
The for freezing point depression ΔT_f is
ΔT_f = iK_fb
where
i = the number of moles of particles available from one mole of solute
K_f = the molal freezing point depression constant
b = the molal concentration of the solute
All your solutions are aqueous NaCl. They differ only in their concentrations.
Thus, the most concentrated solution will have the greatest freezing point depression and the lowest freezing point.
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PH + pOH = 14
pH + 8 = 14
pH= 6