2 years ago

What does the subscript tell you?

Chemistry

1 answer:

OverLord2011 [107]2 years ago

8 0

B. The number of atoms of each element in a formula

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a) ΔHvap=35.3395 kJ/mol

b) Tb=98.62 °C

Explanation:

Given the reaction:

C₇H₁₆ (l) ⇔ C₇H₁₆ (g)

Kp=P(C₇H₁₆) since the concentration ratio for a pure liquid is equal to 1.

When

T₁=50°C=323.15K ⇒P₁=0.179

T₂=86°C=359.15K ⇒P₂=0.669

The Clasius-Clapeyron equation is:

$ln(\frac{P_2}{P_1}) =-\frac{AH_{vap}}{R} (\frac{1}{T_2}-\frac{1}{T_1})$

$ln(\frac{0.669}{0.179}) =-\frac{AH_{vap}}{8.3145 J.mol^{-1}K^{-1}} (\frac{1}{359.15K}-\frac{1}{323.15K})$

$1.3184 =-\frac{AH_{vap}}{8.3145 J.mol^{-1}K^{-1}} (-3.10186*10^{-4}K{^-1})$

ΔHvap=35339.5 J/mol=35.3395 KJ/mol

Normal boiling point ⇒ P=1 atm

Hence, we find the normal boiling point where:

T₁=323.15K

P₁=0.179 atm

P₂=1 atm

$ln(\frac{P_2}{P_1}) =-\frac{AH_{vap}}{R} (\frac{1}{T_2}-\frac{1}{T_1})$

$ln(\frac{1atm}{0.179atm}) =-\frac{35339.5 J/mol}{8.3145 J.mol^{-1}K^{-1}} (\frac{1}{T_2}-\frac{1}{323.15K})$

$1.7203=-4250.34 (\frac{1}{T_2}-\frac{1}{323.15K})$

T₂=371.77 K= 98.62 °C

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