Answer: The expression for equilibrium constant is ![\frac{[NH_3]^2}{[H_2]^3[N_2]}](https://tex.z-dn.net/?f=%5Cfrac%7B%5BNH_3%5D%5E2%7D%7B%5BH_2%5D%5E3%5BN_2%5D%7D)
Explanation: Equilibrium constant is the expression which relates the concentration of products and reactants preset at equilibrium at constant temperature. It is represented as 
For a general reaction:

The equilibrium constant is written as:
![k_c=\frac{[C]^c[D]^d}{[A]^a[B]^b}](https://tex.z-dn.net/?f=k_c%3D%5Cfrac%7B%5BC%5D%5Ec%5BD%5D%5Ed%7D%7B%5BA%5D%5Ea%5BB%5D%5Eb%7D)
Chemical reaction for the formation of ammonia is:


Expression for
is:
![k_c=\frac{[NH_3]^2}{[H_2]^3[N_2]}](https://tex.z-dn.net/?f=k_c%3D%5Cfrac%7B%5BNH_3%5D%5E2%7D%7B%5BH_2%5D%5E3%5BN_2%5D%7D)
![1.6\times 10^2=\frac{[NH_3]^2}{[H_2]^3[N_2]}](https://tex.z-dn.net/?f=1.6%5Ctimes%2010%5E2%3D%5Cfrac%7B%5BNH_3%5D%5E2%7D%7B%5BH_2%5D%5E3%5BN_2%5D%7D)
<u>Answer:</u> The experimental van't Hoff factor is 1.21
<u>Explanation:</u>
The expression for the depression in freezing point is given as:

where,
i = van't Hoff factor = ?
= depression in freezing point = 0.225°C
= Cryoscopic constant = 1.86°C/m
m = molality of the solution = 0.100 m
Putting values in above equation, we get:

Hence, the experimental van't Hoff factor is 1.21
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<span>Answer:
The HCl and KOH will react until one or the other is gone. As you have a larger volume of an equal concentration of HCl, the KOH will go first.
moles HCl = 0.04000 L * 0.100 M = 0.00400 moles
moles KOH = 0.02500 L * 0.100 M = 0.00250 moles
moles HCl left = 0.00400 - 0.00250 = 0.00150 moles
Your total volume is now 65.00 mL, so the [HCl] = 0.00150 moles / 0.06500 L = 0.0231 M = [H+]
pH = -log [H+] = -log (0.0231) = 1.64</span>