Answer:
Kp = 1.41 x 10⁻⁶
Explanation:
We have the chemical equation:
2 A(g) + 3 B(g)⇌ C(g)
In which A and B are the reactants and C is the product. We calculate first the change in the number of moles of gas (Δn or dn):
dn= (sum moles products - sum moles reactants)
= (moles C - (moles A + moles B))
= (1 - (2+3))
= 1 - 5
= -4
We have also the following data:
Kc = 63.2
T= 81∘C + 273 = 354 K
R = 0.082 L.atm/K.mol (it is a constant)
Thus, we introduce the data in the mathematical expression for the relation between Kp and Kc:
= (0.082 L.atm/K.mol x 354 K)⁻⁴ = 1.41 x 10⁻⁶
ΔHrxn = ΣδΗ(bond breaking) - ΣδΗ(bond making)
Bond enthalpies,
N ≡ N ⇒ 945 kJ mol⁻¹
N - Cl ⇒ 192 kJ mol⁻¹
Cl - Cl⇒ 242 kJ mol⁻¹
According to the balanced equation,
ΣδΗ(bond breaking) = N ≡ N x 1 + Cl - Cl x 3
= 945 + 3(242)
= 1671 kJ mol⁻¹
ΣδΗ(bond making) = N - Cl x 3 x 2
= 192 x 6
= 1152 kJ mol⁻¹
δHrxn = ΣδΗ(bond breaking) - ΣδΗ(bond making)
= 1671 kJ mol⁻¹ - 1152 kJ mol⁻¹
= 519 kJ mol⁻¹
Answer:
b- The heat capacity ratio increases but output temperature don’t change
Explanation:
The heat capacity is the amount of energy required to raise the temperature of a body, by 1 degree. On the other hand, the specific heat capacity is the amount of heat required to raise the temperature of a of unit mass of a material by 1 degree.
Heat capacity is an extensive property meaning its value depends on the amount of material. Specific heat capacity is found by dividing heat capacity by the mass of the sample, thus making it independent of the amount (intensive property). So if the specific heat capacity increases and the mass of the sample remains the same, the heat capacity must increase too. Because of that options c and d that say that heat capacity reamins same are INCORRECT.
On the other hand, in which has to be with options a and b both say that the heat capacity increases which is correct, but about the output temperatures what happens is that if we increase the specific heat capacity of both fluids that are involved in a process of heat exchange in the same value, the value of the output temperatures do not change so only option a is CORRECT.