I. define ionic bonding and describe how it can be formed between sodium and chlorine

Express the van der Waals equation of state as a virial expansion in powers of 1/Vm and obtain expressions for B and C in terms

nirvana33 [79]

Answer:

$PV_{m} = RT[1 + (b-\frac{a}{RT})\frac{1}{V_{m} } + \frac{b^{2} }{V^{2} _{m} } + ...]$

B = b -a/RT

C = b^2

a = 1.263 atm*L^2/mol^2

b = 0.03464 L/mol

Explanation:

In the given question, we need to express the van der Waals equation of state as a virial expansion in powers of 1/Vm and obtain expressions for B and C in terms of the parameters a and b. Therefore:

Using the van deer Waals equation of state:

$P = \frac{RT}{V_{m}-b } - \frac{a}{V_{m} ^{2} }$

With further simplification, we have:

$P = RT[\frac{1}{V_{m}-b } - \frac{a}{RTV_{m} ^{2} }]$

Then, we have:

$P = \frac{RT}{V_{m} } [\frac{1}{1-\frac{b}{V_{m} } } - \frac{a}{RTV_{m} }]$

Therefore,

$PV_{m} = RT[(1-\frac{b}{V_{m} }) ^{-1} - \frac{a}{RTV_{m} }]$

Using the expansion:

$(1-x)^{-1} = 1 + x + x^{2} + ....$

Therefore,

$PV_{m} = RT[1+\frac{b}{V_{m} }+\frac{b^{2} }{V_{m} ^{2} } + ... -\frac{a}{RTV_{m} }]$

Thus:

$PV_{m} = RT[1 + (b-\frac{a}{RT})\frac{1}{V_{m} } + \frac{b^{2} }{V^{2} _{m} } + ...]$ equation (1)

Using the virial equation of state:

$P = RT[\frac{1}{V_{m} }+ \frac{B}{V_{m} ^{2}}+\frac{C}{V_{m} ^{3} }+ ...]$

Thus:

$PV_{m} = RT[1+ \frac{B}{V_{m} }+ \frac{C}{V_{m} ^{2} } + ...]$ equation (2)

Comparing equations (1) and (2), we have:

B = b -a/RT

C = b^2

Using the measurements on argon gave B = −21.7 cm3 mol−1 and C = 1200 cm6 mol−2 for the virial coefficients at 273 K.

$b = \sqrt{C} = \sqrt{1200} = 34.64[tex]cm^{3}/mol$ [/tex] = 0.03464 L/mol

a = (b-B)*RT = (34.64+21.7)*(1L/1000cm^3)*(0.0821)*(273) = 1.263 atm*L^2/mol^2

3 0

2 years ago

15 POINTS PLS HELP!!!!!

scZoUnD [109]

Answer: (C) Vaporizing

Explanation:

Vaporization is the process in which the substance change the state of of liquid into the gas state.

The vaporization process require the largest input of the energy as when the state is in the solid state then, the solid substances contain the strong forces of the attraction and they require high energy to break these strong bonds.

For changing the liquid state into the gases state we require to overcome the surface tension and require enough energy for acquiring the vaporization state.

Therefore, option (C) is correct.

5 0

3 years ago

What is the ph of a saturated solution of aluminum hydroxide?

sasho [114]

Answer is attached below ( sorry for mistake )

6 0

3 years ago

1. Silver nitrate will react with aluminum metal, yielding aluminum nitrate and silver metal. If you start with 0.223 moles of a

Archy [21]

Answer:

Explanation:

1)

Given data:

Number of moles of aluminium = 0.223 mol

Mass of silver produced = ?

Solution:

Chemical equation:

3AgNO₃ + Al → 3Ag + Al(NO₃)₃

Now we will compare the moles of Al with silver.

Al : Ag

1 : 3

0.223 : 3×0.223= 0.669 mol

Grams of silver:

Mass = number of moles × molar mass

Mass = 0.669 mol × 107.87 g/mol

Mass = 72.2 g

2)

Given data:

Number of moles of mercury(II) oxide produced = 3.12 mol

Mass of mercury = ?

Solution:

Chemical equation:

2Hg + O₂ → 2HgO

Now we will compare the moles of mercury with mercury(II) oxide.

HgO : Hg

2 : 2

3.12 : 3.12

Mass of Hg:

Mass = number of moles × molar mass

Mass = 3.12 mol × 200.59 g/mol

Mass = 625.84 g

3)

Given data:

Number of moles of dinitrogen pentoxide = 12.99 mol

Mass of oxygen = ?

Solution:

Chemical equation:

2N₂ + 5O₂ → 2N₂O₅

Now we will compare the moles of N₂O₅ with oxygen.

N₂O₅ : O₂

2 : 5

12.99 : 5/2×12.99 = 32.48 mol

Mass of oxygen:

Mass = number of moles × molar mass

Mass = 32.48 mol × 32 g/mol

Mass = 1039.36 g

4)

Given data:

Number of moles of benzene = 0.103 mol

Mass of carbon dioxide = ?

Solution:

Chemical equation:

2C₆H₆ + 15O₂ → 12CO₂ + 6H₂O

Now we will compare the moles of N₂O₅ with oxygen.

C₆H₆ : CO₂

2 : 12

0.103 : 12/2×0.103 = 0.618 mol

Mass of carbon dioxide:

Mass = number of moles × molar mass

Mass = 0.618 mol × 44 g/mol

Mass = 27.192 g

3 0

3 years ago

PLEASE HELP AND THANKS

Kamila [148]

Answer:

torque =force*distance

4 0

3 years ago