The mass of piece of sterling silver jewelry is 33.24 g. It contains 92.5% silver Ag by mass. Since, sterling silver is an alloy of Ag-Cu thus, percentage of Cu will be:
% Cu=100-92.5=7.5%
Thus, mass of copper will be:

Molar mass of Cu is 63.546 g/mol, thus, number of moles of Cu can be calculated as follows:

Here, m is mass and M is molar mass.
Putting the values,

Now, in 1 mole of Cu there are
thus, in 0.03923 mol, number of Cu atoms will be:

Thus, number of atoms of Cu will be
.
Explanation:
Due to the positive value of the change in temperature, this is an endothermic reaction.
Since the forward reaction is endothermic, increasing the temperature increases the equilibrium constant (k).
In an equilibrium system, the position of the equilibrium will move in a way to annul the change made to the system. An increase in temperature for an endothermic reaction would favour the reaction, leading to increase in amount of products and decrease in amount of reactants.
Explanation:
temperature changes affect seawater density as water cools its density increases. As water cools H2O molecules pack more closely together because the molecules are vibrating less at low temperatures and take up less volume. The same number of water molecules in smaller volume results higher density
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