Answer:
a, and f.
Explanation:
To be deprotonated, the conjugate acid of the base must be weaker than the acid that will react, because the reactions favor the formation of the weakest acid. The pKa value measures the strength of the acid. As higher is the pKa value, as weak is the acid. So, let's identify the conjugate acid and their pKas:
a. NaNH2 will dissociate, and NH2 will gain the proton and forms NH3 as conjugate acid. pKa = 38.0, so it happens.
b. NaOH will dissociate, and OH will gain the proton and forms H2O as conjugate acid. pKa = 14.0, so it doesn't happen.
c. NaC≡N will dissociate, and CN will gain a proton and forms HCN as conjugate acid. pKa = 9.40, so it doesn't happen.
d. NaCH2(CO)N(CH3)2 will dissociate and forms CH3(CO)N(CH3)2 as conjugate acid. pKa = -0.19, so it doesn't happen.
e. H2O must gain one proton and forms H3O+. pKa = -1.7, so it doesn't happen.
f. CH3CH2Li will dissociate, and the acid will be CH3CH3. pKa = 50, so it happens.
Measuring the surface of an oil painting and finding its dimensions 12 to be 12 inches
Answer : The value of 
for the reaction is -959.1 kJ
Explanation :
The given balanced chemical reaction is,
First we have to calculate the enthalpy of reaction 
.
![\Delta H^o=[n_{H_2O}\times \Delta H_f^0_{(H_2O)}+n_{SO_2}\times \Delta H_f^0_{(SO_2)}]-[n_{H_2S}\times \Delta H_f^0_{(H_2S)}+n_{O_2}\times \Delta H_f^0_{(O_2)}]](https://tex.z-dn.net/?f=%5CDelta%20H%5Eo%3D%5Bn_%7BH_2O%7D%5Ctimes%20%5CDelta%20H_f%5E0_%7B%28H_2O%29%7D%2Bn_%7BSO_2%7D%5Ctimes%20%5CDelta%20H_f%5E0_%7B%28SO_2%29%7D%5D-%5Bn_%7BH_2S%7D%5Ctimes%20%5CDelta%20H_f%5E0_%7B%28H_2S%29%7D%2Bn_%7BO_2%7D%5Ctimes%20%5CDelta%20H_f%5E0_%7B%28O_2%29%7D%5D)
where,
= enthalpy of reaction = ?
n = number of moles
= standard enthalpy of formation
Now put all the given values in this expression, we get:
![\Delta H^o=[2mole\times (-242kJ/mol)+2mole\times (-296.8kJ/mol)}]-[2mole\times (-21kJ/mol)+3mole\times (0kJ/mol)]](https://tex.z-dn.net/?f=%5CDelta%20H%5Eo%3D%5B2mole%5Ctimes%20%28-242kJ%2Fmol%29%2B2mole%5Ctimes%20%28-296.8kJ%2Fmol%29%7D%5D-%5B2mole%5Ctimes%20%28-21kJ%2Fmol%29%2B3mole%5Ctimes%20%280kJ%2Fmol%29%5D)
conversion used : (1 kJ = 1000 J)
Now we have to calculate the entropy of reaction 
.
![\Delta S^o=[n_{H_2O}\times \Delta S_f^0_{(H_2O)}+n_{SO_2}\times \Delta S_f^0_{(SO_2)}]-[n_{H_2S}\times \Delta S_f^0_{(H_2S)}+n_{O_2}\times \Delta S_f^0_{(O_2)}]](https://tex.z-dn.net/?f=%5CDelta%20S%5Eo%3D%5Bn_%7BH_2O%7D%5Ctimes%20%5CDelta%20S_f%5E0_%7B%28H_2O%29%7D%2Bn_%7BSO_2%7D%5Ctimes%20%5CDelta%20S_f%5E0_%7B%28SO_2%29%7D%5D-%5Bn_%7BH_2S%7D%5Ctimes%20%5CDelta%20S_f%5E0_%7B%28H_2S%29%7D%2Bn_%7BO_2%7D%5Ctimes%20%5CDelta%20S_f%5E0_%7B%28O_2%29%7D%5D)
where,
= entropy of reaction = ?
n = number of moles
= standard entropy of formation
Now put all the given values in this expression, we get:
![\Delta S^o=[2mole\times (189J/K.mol)+2mole\times (248J/K.mol)}]-[2mole\times (206J/K.mol)+3mole\times (205J/K.mol)]](https://tex.z-dn.net/?f=%5CDelta%20S%5Eo%3D%5B2mole%5Ctimes%20%28189J%2FK.mol%29%2B2mole%5Ctimes%20%28248J%2FK.mol%29%7D%5D-%5B2mole%5Ctimes%20%28206J%2FK.mol%29%2B3mole%5Ctimes%20%28205J%2FK.mol%29%5D)
Now we have to calculate the Gibbs free energy of reaction 
.
As we know that,
At room temperature, the temperature is 500 K.
Therefore, the value of for the reaction is -959.1 kJ
Answer:
P₂ = 1312.88 atm
Explanation:
Given data:
Initial temperature = 25°C
Initial pressure = 1250 atm
Final temperature = 40°C
Final pressure = ?
Solution:
Initial temperature = 25°C (25+273.15 = 298.15 K)
Final temperature = 40°C ( 40+273.15 = 313.15 k)
The pressure of given amount of a gas is directly proportional to its temperature at constant volume and number of moles.
Mathematical relationship:
P₁/T₁ = P₂/T₂
Now we will put the values in formula:
1250 atm / 298.15 K = P₂/313.15 K
P₂ = 1250 atm × 313.15 K / 298.15 K
P₂ = 391437.5 atm. K /298.15 K
P₂ = 1312.88 atm
