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vitfil [10]
3 years ago
14

Acidified solutions of sodium dichromate, K 2 Cr 2 O 7 , and copper (I) bromide, CuBr, are mixed.

Chemistry
1 answer:
Nina [5.8K]3 years ago
6 0

Answer:

Cr_2O_7^{2-}(aq)+2Cu^+(aq)\rightarrow Cu_2Cr_2O_7(s)

Explanation:

Hello!

In this case, when writing net ionic equations, we first need to identify the complete molecular equation; thus for potassium dichromate reacting with copper (I) bromide, we have:

K_2Cr_2O_7(aq)+2CuBr(aq)\rightarrow Cu_2Cr_2O_7(s)+2KBr(aq)

Thus, since all the species are aqueous except copper (II) dichromate, we can write the complete ionic equation by ionizing the aqueous ones:

2K^++Cr_2O_7^{2-}+2Cu^++2Br^-\rightarrow Cu_2Cr_2O_7(s)+2K^++2Br^-

Finally, for the net ionic equation, we need to cancel out the spectator ions as they are present at both reactants and products sides, thus, we obtain:

Cr_2O_7^{2-}(aq)+2Cu^+(aq)\rightarrow Cu_2Cr_2O_7(s)

Best regards!

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A 100.0 mL sample of 0.300 M NaOH is mixed with a 100.0 mL sample of 0.300 M HNO3 in a coffee cup calorimeter. If both solutions
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Answer:

\boxed{\text{-55.8 kJ/mol NaOH}}

Explanation:

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\begin{array}{cccl}\text{Heat from neutralization} & + &\text{Heat absorbed by water} & = 0\\q_{1} & + & q_{2} & =0\\n\DeltaH & + & mC\Delta T & =0\\\end{array}

Data:

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Calculations:

(a) q₁

n_{\text{NaOH}} = \text{0.1000 L } \times \dfrac{\text{0.300 mol}}{\text{1 L}} = \text{0.0300 mol}\\\\n_{\text{HNO}_{3}} = \text{0.1000 L } \times \dfrac{\text{0.300 mol}}{\text{1 L}} = \text{0.0300 mol}

We have equimolar amounts of NaOH and HNO₃

n = 0.0300 mol

q₁ = 0.0300ΔH

(b) q₂

 V = 100.0 mL + 100.0 mL = 200.0 mL

m = 200.0 g

ΔT = T₂ - T₁ = 37.00 °C – 35.00 °C = 2.00 °C

q₂ = 200.0 × 4.184 × 2.00 = 1674 J

(c) ΔH

0.0300ΔH + 1674 = 0

          0.0300ΔH = -1674

                      ΔH = -1674/0.0300

                      ΔH = -55 800 J/mol

                      ΔH = -55.8 kJ/mol

\Delta_{r}H^{\circ} = \boxed{\textbf{-55.8 kJ/mol NaOH}}

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