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Explanation:
Copper(II) sulfide reacts with oxygen gas to give solid copper(II) oxide and sulfur trioxide gas.
The reaction is given as:

When 1 mol copper(II) sulfide react with 2 moles of oxygen gas it gives 1 mol of solid copper(II) oxide and 1 mol of sulfur trioxide gas
The gas formed in above reaction that is sulfur trioxide reacts with water to give sulfuric acid or hydrogen sulfate.
The reaction is given as:

1 mol of sulfur trioxide gas reacts with 1 mol of liquid water to produce 1 molo of liquid hydrogen sulfate or sulfuric acid
The molarity of NaOH needed is calculated as follows
calculate the moles of KhC8h4O4
that is moles = mass/molar mass of KhC8h4O4(204.22 g/mol)
=0.5632g /204.22g/mol= 2.76 x10^-3 moles
write the equation for reaction
khc8h4O4 + NaOH ---> KNaC8h4O4 + H2O
from the equation above the reacting ratio of KhC8h4O4 to NaOh is 1:1 therefore the moles of Naoh is also 2.76 x10^-3 moles
molarity of NaOh = (moles of NaOh / volume ) x 1000
that is { (2.76 x10^-3) / 23.64} x100 =0.117 M