Answer:
The correct answer is - 4-nitroaniline.
Explanation:
It is given that all three solid compounds salicylic acid + 4-nitroaniline + naphthalene are equal in the ratio in the mixture and then 1 gram of this mixture is dissolved in the diethyl ether and run a drop of the solution on TLC plate. This plate shows three spots.
The salicylic acid and naphthalene would stay dissolved in the diethyl ether solution due to the 4-nitroaniline could be extracted by adding aqueous acid and involve in the aqueous layer and thus spot of 4-nitroaniline would be with largest Rf value.
Answer:
Explanation:
The expected product is MgO, so the 1-to-1 mole ratio Mg to O in the product is all that is required.
Answer:
The correct order of increasing reactivity toward nucleophilic acyl substitution is E < D < C < A < F < B.
Explanation:
The stability of the leaving group best determines the manner of reactivity of carboxylates to nucleophilic substitution after the substitution of the nucleophile to the leaving group. The leaving group should, therefore, be protonated with hydrogen ion in the solution to form a stable molecule. From the given list: The leaving group for A, Ethyl thioacetate will be ethanethiol. For B, Acetyl chloride will be Hydrochloric acid. For C, Sodium acetate will be Sodium Hydroxide. For D, Ethyl acetate will be Ethanol. For E, Acetamide will be Ammonia, and for F, Acetic anhydride will be Ethanoic acid. The reactivity of the substitution reaction is dependent on the stability of these leaving groups. The stability of these leaving groups depends on their pKa, and the more the pKa, the lesser the acidity of the leaving group, and the lower the reactivity. Therefore, considering their pKa: A is 8.5, B is -7, C is 13.8, D is 15.9, E is 36, and F is 4.8. When we rearrange this pKa in descending order, we have E, D. C, A, F, B. Which is also the increased reactivity of the nucleophilic acyl substitution.
To
determine the percent ionization of the acid given, we make use of the acid
equilibrium constant (Ka) given. It is the ration of the equilibrium
concentrations of the dissociated ions and the acid. The dissociation reaction
of the HF acid would be as follows:<span>
HF = H+ + F-
The acid equilibrum constant would be expressed as follows:
Ka = [H+][F-] / [HF] = 3.5 x 10-4
To determine the equilibrium concentrations we use the ICE table,
HF
H+ F-
I 0.337 0
0
C -x +x
+x
---------------------------------------------
E 0.337-x x
x
3.5 x 10-4 = [H+][F-] / [HF]
3.5 x 10-4 = [x][x] / [0.337-x] </span>
Solving for x,
x = 0.01069 = [H+] = [F-]
percent ionization = 0.01069 / 0.337 x 100 = 3.17%
Constant variable/control variable
