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ElenaW [278]
3 years ago
8

A 20.0 % by mass solution of phosphoric acid (H 3PO 4) in water has a density of 1.114 g/mL at 20°C. What is the molarity of thi

s solution?
Chemistry
1 answer:
Vinvika [58]3 years ago
6 0

Answer:

2.28 M

Explanation:

Step 1: Given data

Percent by mass (%m/m): 20.0 %

Density (ρ): 1.114 g/mL

Step 2: Calculate the percent by volume (%m/v)

We will use the following expression.

\% m/v = \% m/m \times \rho = 20.0 \%  \times 1.114g/mL = 22.3 g \% mL

Step 3: Calculate the moles of solute in 100 mL of solution

The molar mass of phosphoric acid is 97.99 g/mol. The moles corresponding to 22.3 g are:

22.3g \times \frac{1mol}{97.99g} = 0.228mol

Step 4: Calculate the molarity of the solution

0.228 moles of solute are in 100 mL (0.100 L) of solution. The molarity of the solution is:

M = \frac{0.228mol}{0.100L} =2.28 M

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Calculate the volume in mL of 0.279 M Ca(OH)2 needed to neutralize 24.5 mL of 0.390 M H3PO4 in a titration.
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The volume of the 0.279 M Ca(OH)₂ solution required to neutralize 24.5 mL of 0.390 M H₃PO₄ is 51.4 mL

<h3>Balanced equation </h3>

2H₃PO₄ + 3Ca(OH)₂ —> Ca₃(PO₄)₂ + 6H₂O

From the balanced equation above,

  • The mole ratio of the acid, H₃PO₄ (nA) = 2
  • The mole ratio of the base, Ca(OH)₂ (nB) = 3

<h3>How to determine the volume of Ca(OH)₂ </h3>
  • Molarity of acid, H₃PO₄ (Ma) = 0.390 M
  • Volume of acid, H₃PO₄ (Va) = 24.5 mL
  • Molarity of base, Ca(OH)₂ (Mb) = 0.279 M
  • Volume of base, Ca(OH)₂ (Vb) =?

MaVa / MbVb = nA / nB

(0.39 × 24.5) / (0.279 × Vb) = 2/3

9.555 / (0.279 × Vb) = 2/3

Cross multiply

2 × 0.279 × Vb = 9.555 × 3

0.558 × Vb = 28.665

Divide both side by 0.558

Vb = 28.665 / 0.558

Vb = 51.4 mL

Thus, the volume of the Ca(OH)₂ solution needed is 51.4 mL

Learn more about titration:

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